Provided in one example herein is a three-dimensional (“3D”) printing method, comprising: (A) forming a layer comprising particles comprising a thermoplastic; (B) disposing over at least a portion of the layer a coalescent agent, which is radiation-absorbing and has a thermal decomposition temperature lower than or equal a melting temperature of the thermoplastic; (C) forming an object slice of a 3D object by exposing the coalescent agent to a radiant energy such that at least some of the coalescent agent thermally decomposes while causing at least some of the particles to fuse, wherein the object slice comprises the fused particles, and wherein the thermally decomposed coalescent agent is not radiation-absorbing; and (D) repeating (A) to (C) to form the 3D object comprising multiple object slices bound depth-wise to one another.