Disclosed is an electrode structure including an electrode body, a composite layer disposed on the electrode body; a surface of the composite layer away from the electrode body being set to be a finger contact surface in a case of fingerprint recognition, wherein the composite layer is made from composite materials formed by a cured main body glue and one-dimensional nano-conductor materials distributed in the main body glue; and an end of each of the one-dimensional nano-conductor materials exposed from the finger contact surface of the composite layer, and the other of each of the one-dimensional nano-conductor materials makes contact with the electrode body. A fingerprint recognition module including the electrode structure and a manufacturing method thereof are also disclosed.