A high-strength steel sheet with excellent formability and high yield ratio that has TS of 590 MPa or more and YR of 68% or more is obtained by providing a predetermined chemical composition and a steel microstructure that contains, in area ratio, 35 to 80% of polygonal ferrite, 5% or more of non-recrystallized ferrite, and 5 to 25% of martensite, and that contains, in volume fraction, 8% or more of retained austenite, in which the polygonal ferrite has a mean grain size of 6 μm or less, the martensite has a mean grain size of 3 μm or less, the retained austenite has a mean grain size of 3 μm or less, and a value obtained by dividing an Mn content in the retained austenite (in mass %) by an Mn content in the polygonal ferrite (in mass %) equals 2.0 or more.