- 专利标题: PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID
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申请号: US15746082申请日: 2016-07-01
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公开(公告)号: US20180215724A1公开(公告)日: 2018-08-02
- 发明人: Alvaro Gordillo , Holger Werhan , Richard Dehn , Benoit Blank , Joaquim Henrique Teles , Stephan A Schunk , Markus Piepenbrink , Rene Backes , Lei Zhang
- 申请人: BASF SE
- 优先权: EP15177884.2 20150722
- 国际申请: PCT/EP2016/065494 WO 20160701
- 主分类号: C07D307/46
- IPC分类号: C07D307/46 ; B01J23/42 ; B01J21/18
摘要:
A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.
公开/授权文献
- US10385033B2 Process for preparing furan-2,5-dicarboxylic acid 公开/授权日:2019-08-20
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