公开(公告)号：US10259797B2

公开(公告)日：2019-04-16

申请号：US15772207

申请日：2016-11-03

申请人： BASF SE

发明人： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A Schunk ,  Ivana Jevtovikj ,  Holger Werhan ,  Svenia Duefert ,  Markus Piepenbrink ,  Rene Backes ,  Richard Dehn

IPC分类号： C07D307/50 ,  C07D307/46

摘要： Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US10385033B2

公开(公告)日：2019-08-20

申请号：US15746082

申请日：2016-07-01

申请人： BASF SE

发明人： Alvaro Gordillo ,  Holger Werhan ,  Richard Dehn ,  Benoit Blank ,  Joaquim Henrique Teles ,  Stephan A Schunk ,  Markus Piepenbrink ,  Rene Backes ,  Lei Zhang

IPC分类号： C07D307/02 ,  C07D307/46 ,  B01J21/18 ,  B01J23/42

摘要： A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

公开(公告)号：US12110368B2

公开(公告)日：2024-10-08

申请号：US17275070

申请日：2019-09-06

申请人： BASF SE

发明人： Martin Weber ,  Christian Maletzko ,  Rene Backes

IPC分类号： C08G75/23 ,  A23L2/74 ,  B01D69/08 ,  B01D71/68 ,  C02F1/44 ,  C08G65/40 ,  D01F6/76

CPC分类号： C08G75/23 ,  A23L2/74 ,  B01D69/08 ,  B01D71/68 ,  C02F1/44 ,  C08G65/4056 ,  D01F6/765 ,  A23V2002/00 ,  D10B2505/04

摘要： A polyarylene ether sulfone comprising in polymerized form A) isosorbide, isomannide, isoidide or a mixture thereof and B) at least one nonsulfonated dihalodiaryl! sulfone (compound B) and C) at least one sulfonated dihalodiaryl sulfone (compound C), a process for its preparation and its use in the preparation of coatings, films, fibers, foams, membranes or molded articles.

公开(公告)号：US12091485B2

公开(公告)日：2024-09-17

申请号：US17275558

申请日：2019-09-06

申请人： BASF SE

发明人： Martin Weber ,  Christian Maletzko ,  Rene Backes

IPC分类号： C08F293/00 ,  B01D53/22 ,  B01D69/08 ,  B01D71/52 ,  B01D71/68 ,  B01D71/80 ,  C09D153/00 ,  D01F6/66 ,  D01F6/76

CPC分类号： C08F293/00 ,  B01D53/228 ,  B01D69/08 ,  B01D71/522 ,  B01D71/68 ,  B01D71/80 ,  C09D153/00 ,  D01F6/665 ,  D01F6/765

摘要： A polyarylene ether copolymer comprising i) at least one block comprising in polymerized form A) isosorbide, isomannide, isoidide or a mixture thereof and B) at least one unit comprising at least one difunctional compound comprising at least one dichlorodiaryl sulfone, a dichlorodiaryl ketone or a mixture thereof and ii) at least one block comprising in polymerized form C) at least one polyalkylene oxide, a process for its preparation and its use in the preparation of coatings, films, fibers, foams, membranes or molded articles.

公开(公告)号：US20180319759A1

公开(公告)日：2018-11-08

申请号：US15772207

申请日：2016-11-03

申请人： BASF SE

发明人： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A Schunk ,  Ivana Jevtovikj ,  Holger Werhan ,  Svenia Duefert ,  Markus Piepenbrink ,  Rene Backes ,  Richard Dehn

IPC分类号： C07D307/50

CPC分类号： C07D307/50 ,  C07D307/46

摘要： Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US12091503B2

公开(公告)日：2024-09-17

申请号：US17275590

申请日：2019-09-06

申请人： BASF SE

发明人： Martin Weber ,  Feelly Ruether ,  Rene Backes ,  Christian Maletzko

IPC分类号： C08G65/42 ,  B01D71/52 ,  C08G65/40 ,  C08G75/23 ,  C08G101/00

CPC分类号： C08G65/4012 ,  B01D71/522 ,  C08G65/42 ,  C08G75/23 ,  C08G2101/00 ,  C08G2150/00 ,  C08G2650/40

摘要： A polyarylene ether comprising in polymerized form A) at least one tri- or higher functional compound and B) isosorbide. isomannide, isoidide or a mixture thereof, wherein the polyarylene ether is a polyarylene ether sulfone or a polyarylene ether ketone, ¢ process for its preparation and its use in the preparation of a coating, film, fiber, foam, membrane or molded article.

公开(公告)号：US10428039B2

公开(公告)日：2019-10-01

申请号：US15773411

申请日：2016-11-03

申请人： BASF SE

发明人： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A. Schunk ,  Ivana Jevtovikj ,  Rene Backes ,  Holger Werhan ,  Svenia Duefert ,  Richard Dehn ,  Markus Piepenbrink

IPC分类号： C07D307/02 ,  C07D307/46 ,  C07D307/68

摘要： Provided herein is a process for preparing furan-2,5-dicarboxylic acid. The process includes the following steps: (A-1) preparing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of: hexoses, oligosaccharides comprising hexose units, and polysaccharides including hexose units, and as a solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of a formula (II) and (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, resulting in a mixture including 5-(hydroxymethyl)furfural and/or the one or more HMF esters of a formula (I), one or more carboxylic acids of a formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US20180319758A1

公开(公告)日：2018-11-08

申请号：US15773411

申请日：2016-11-03

申请人： BASF SE

发明人： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A Schunk ,  Ivana Jevtovikj ,  Rene Backes ,  Holger Werhan ,  Svenia Duefert ,  Richard Dehn ,  Markus Piepenbrink

IPC分类号： C07D307/46

CPC分类号： C07D307/46 ,  C07D307/68

摘要： Provided herein is a process for preparing furan-2,5-dicarboxylic acid. The process includes the following steps: (A-1) preparing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of: hexoses, oligosaccharides comprising hexose units, and polysaccharides including hexose units, and as a solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of a formula (II) and (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, resulting in a mixture including 5-(hydroxymethyl)furfural and/or the one or more HMF esters of a formula (I), one or more carboxylic acids of a formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US20180215724A1

公开(公告)日：2018-08-02

申请号：US15746082

申请日：2016-07-01

申请人： BASF SE

发明人： Alvaro Gordillo ,  Holger Werhan ,  Richard Dehn ,  Benoit Blank ,  Joaquim Henrique Teles ,  Stephan A Schunk ,  Markus Piepenbrink ,  Rene Backes ,  Lei Zhang

IPC分类号： C07D307/46 ,  B01J23/42 ,  B01J21/18

CPC分类号： C07D307/46 ,  B01J21/18 ,  B01J23/42

摘要： A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

公开(公告)号：US20170305871A1

公开(公告)日：2017-10-26

申请号：US15517576

申请日：2015-08-12

申请人： BASF SE

发明人： Dominik Ohlmann ,  Markus Dierker ,  Vanessa Puetz ,  Stefan Busch ,  Rene Backes ,  Anne Van Den Wittenboer

IPC分类号： C07D307/20 ,  A61K47/22 ,  A61K8/49 ,  A61Q19/00 ,  C12P17/04 ,  C11D1/66

CPC分类号： C07D307/20 ,  A61K8/4973 ,  A61K47/22 ,  A61K2800/10 ,  A61Q19/00 ,  C07D307/12 ,  C11D1/667 ,  C12P17/04 ,  C12Y301/01003

摘要： The present invention relates to novel mono- and diesters of 2,5-di(hydroxymethyl)tetrahydrofuran, processes for their preparation by esterification in the presence of tertiary amines or in the presence of enzymatic esterification catalysts and the use of these mono- and diesters as interface-active compounds, rheology modifiers and emollients. The invention further relates to cosmetic and pharmaceutical compositions, and to detergents, cleaners and dishwashing compositions which comprise these mono- and diesters of 2,5-di(hydroxymethyl)-tetrahydrofuran.