The invention relates to a method for producing special nanocapsules, which can be used as thermolatent polymerization catalysts, in particular for the polarization of polyurethanes, by means of a high shear process, wherein the method comprises: (i) emulsification of a reaction mixture into a continuous aqueous phase comprising at least one stabilizer, wherein the reaction mixture comprises, based on the total weight of the reaction mixture: (a) 10.0 to 99.0 wt. % of a monomer mixture which comprises, based on the total weight of the monomer mixture: (a1) 2.5 to 19.0 wt. % of at least one simply ethylenically unsaturated C3-5-carboxylic acid monomer; (a2) 76.0 to 97.5 wt. % of at least one simply ethylenically unsaturated C3-5-carboxylic acid-C1-10-alkyl ester monomer; (a3) 0.0 to 5.0 wt. % of at least one monomer which bears at least two ethylenically unsaturated groups; (b) 1.0 to 70.0 wt. % of at least one polymerization catalyst or initiator; (c) 0.0 to 89.0 wt. % of at least one hydrophobic release agent, wherein the release agent preferably has a Hansen parameter ∂t of less than 20; and (d) 0.0 to 10.0 wt. % of at least one ultrahydrophobic compound which is different from the release agent; (ii) optionally homogenizing the emulsion from step (i); and (iii) polymerizing the monomers. The invention further relates to the nanocapsules produced by means of the described methods, to the use thereof, and to agents which contain these nanocapsules.