- 专利标题: HYDROGENATION METHOD FOR PREPARING HYDROGENATED BISPHENOL-A HAVING A HIGHER TRANS/TRANS ISOMER RATIO
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申请号: US15990871申请日: 2018-05-29
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公开(公告)号: US20180346398A1公开(公告)日: 2018-12-06
- 发明人: Te-Chao LIAO , Jung-Jen CHUANG , Chung-Yu CHEN , Chia-Ruey TSAI , Sung-Chieh CHAO
- 申请人: NAN YA PLASTICS CORPORATION
- 优先权: TW106117969 20170531
- 主分类号: C07C29/20
- IPC分类号: C07C29/20 ; B01J23/46
摘要:
A hydrogenation method for preparing HBPA includes placing a BPA reaction liquid into a hydrogenation vessel with a hollow-shaft stirrer installed inside; starting the hollow-shaft stirrer to stir the BPA reaction liquid and simultaneously allowing hydrogen gas evenly distributed over and contact well with the BPA reaction liquid; in the presence of a single-metallic Ru/Al2O3 hydrogenation catalyst to proceed with a catalytic hydrogenation at low temperature and low pressure to produce HBPA, the HBPA has a yield of 99.7% or more, and particularly having a trans/trans isomer ratio above 63%.
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