Abstract:
A process for producing polyphenylene ether involves to keep a combustible solvent at a gaseous concentration below the minimums of explosion, to keep oxygen gas supplied at a gaseous concentration below the limiting oxygen concentration (LOC) of the solvent, and to make use of a reactor having a rotary-sealed mixer sealed with magnetic rotary feedthroughs to prevent static electricity generated, and then to improve safety and yield thereof.
Abstract:
A hydrogenation method for preparing HBPA includes placing a BPA reaction liquid into a hydrogenation vessel with a hollow-shaft stirrer installed inside; starting the hollow-shaft stirrer to stir the BPA reaction liquid and simultaneously allowing hydrogen gas evenly distributed over and contact well with the BPA reaction liquid; in the presence of a single-metallic Ru/Al2O3 hydrogenation catalyst to proceed with a catalytic hydrogenation at low temperature and low pressure to produce HBPA, the HBPA has a yield of 99.7% or more, and particularly having a trans/trans isomer ratio above 63%.
Abstract:
A process for preparing PPE microspore dispersion includes steps of: dissolving a high-molecular polyphenylene ether in a first solvent at 45-110° C. to form a dissolution liquid; adding processing aids and well mixing the dissolution liquid into a dispersed phase; cooling the dissolution liquid to 42-80° C., and adding a second solvent to generate PPE microspores via PPE to wrap around the processing aids; cooling the dissolution liquid to 0-40° C. to obtain PPE microspore dispersions for use in application for impregnation processes performed below 40° C., thereby high-temperature impregnation equipment are no longer needed, and copper clad laminates made of using the PPE microspore dispersion enjoy excellent physical properties including high Tg, low Dk, low Df and high copper foil's peel strength.
Abstract:
A treatment method of waste fabric containing polyester fiber and elastic fiber is provided. The method includes the steps of using at least one polar solvent to perform at least a two-stage separation treatment on the waste fabric and recycling the waste fabric after the treatment. The at least one polar solvent is selected from the group consisting of dimethylformamide (DMF), dimethylacetamide (DMAC), N-methylpyrrolidone (NMP), gamma-butyrolactone (GBL), and dimethylsulfoxide (DMSO).
Abstract:
A method for preparing N,N′-bis(2-cyanoethyl-1,2-ethylenediamine involves using glycol ether as a catalyst for synthesis reaction in which ethylenediamine and acrylonitrile at a molar ratio of 1:1.9-2.1 are reactant that react at 20-70°C to prepare N,N′-bis(2-cyanoethyl)-1,2-ethylenediamine; the method improves the yield to 98.15-98.98%; and the used glycol ether may be filtered and recycled, thereby saving costs and reducing environmental pollution.
Abstract:
A method is disclosed for use in reducing chemical oxygen demand (COD) of alkaline wastewater generated from an aldol condensation reaction during a process for preparing 2-ethylhexanol, which teaches both high-boiling-point aldol mixtures and low-boiling-point aldol mixtures are used to serve as an extractant for reducing COD in the wastewater, and further to perform a stripping treatment, thereby a removal rate of COD in the wastewater of 89-93% is then achieved.
Abstract:
A process for producing 2-ethylhexanal involves performing reaction using a reaction tank equipped with a gas-introducing mixer having extracting, exhausting, and stirring functions in the presence of a palladium on carbon catalyst having a carbon carrier with lower impurity content and higher specific surface area for hydrogenation, and introducing hydrogen gas evenly into reaction liquid; resulted in that the process minimizes operational pressure for hydrogenation and increases a yield of 2-ethylhexanal at least up to 98.0%.
Abstract:
A method for preparing N,N′-bis(2-cyanoethyl)-1,2-ethylenediamine involves using strongly acidic cation exchange resin as a catalyst for synthesis, and is advantageous for not only eliminating the need of distillation for purification and thereby reducing reaction time, but also improving the yield of N,N′-bis(2-cyanoethyl)-1,2-ethylenediamine to 97.70-98.08%; and the method benefits simplified process and reduced costs and helps to save water significantly, thereby minimizing environmental pollution.
Abstract:
A method for preparing a low migration plasticizer of di-2-ethylhexyl phthalate is provided. The method includes a step of adding at least one short chain alcohol component and at least one long chain alcohol component in an esterification reaction between terephthalic acid and 2-ethylhexanol, so as to graft modify a resulting di-2-ethylhexyl phthalate. The esterification reaction is carried out under a temperature from 30° C. to 225° C. and a pressure from 80 mbar to 1033 mbar.
Abstract:
A method for enhancing reaction efficiency of a terephthalate plasticizer involves using a homogenizer to fine PTA to slurry having a particle size of 80-110 μm, and esterifying the PTA slurry with a C6-C10 alcohol in the presence of a titanium-based catalyst. The reactivity is enhanced by more than 37.5%, and the terephthalate plasticizer so synthetized is low-odor and has a purity of more than 99.5% as well as good physical properties such as acid value, color, and index of refraction.