The present disclosure provides a non-destructive detecting method for weld residual stress and a probe using the same, in the above method, detecting is performed by an ultrasonic detecting probe in contact with a detected portion of a workpiece to be detected, wherein when the weld residual stress of an intersecting curve weld bead of surfaces of cylinders is detected, for the same position of the intersecting curve weld bead, one of the residual stress of an axial direction of the cylinders and the residual stress of a circumferential direction of the cylinders is detected as a principal stress. For the surface of the cylinder at one side of the intersecting curve weld bead, the detecting of the weld residual stress of the surface of the cylinder can be realized only by using an ultrasonic detecting probe having one type of curved surface.