The present disclosure provides films made of polyethylene (PE) compositions. In at least one embodiment, a film includes a polyethylene composition, comprising: ethylene content and from 0 to 25 mol % of C3-C40 olefin comonomer content, based upon the total weight of the polyethylene composition, the polyethylene composition having a total internal plus terminal unsaturation greater than 0.7 unsaturations per 1000 carbon atoms, the film having: an Elmendorf Tear value in the machine direction of from 10 g/mil to 300 g/mil, and a Dart Drop Impact of from 100 g/mil to 800 g/mil. In at least one embodiment, the present disclosure provides for processes to make a film.