发明申请
- 专利标题: METHOD OF MAKING AEI-TYPE ZEOLITES HAVING A HIGH SILICA TO ALUMINA RATIO (SAR)
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申请号: US17271233申请日: 2019-08-23
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公开(公告)号: US20210323832A1公开(公告)日: 2021-10-21
- 发明人: Yunkui Li , David Shepard , De Gao , Wei Wu , Jeffery Lachapelle , Geng Zhang
- 申请人: Pacific Industrial Development Corporation
- 申请人地址: US MI Ann Arbor
- 专利权人: Pacific Industrial Development Corporation
- 当前专利权人: Pacific Industrial Development Corporation
- 当前专利权人地址: US MI Ann Arbor
- 国际申请: PCT/US2019/047828 WO 20190823
- 主分类号: C01B39/48
- IPC分类号: C01B39/48 ; B01J29/76 ; B01J35/02 ; B01J35/10 ; B01J37/04 ; B01J37/00 ; B01J37/10 ; B01J37/03 ; B01J37/30
摘要:
A method of forming an AEI-type zeolite in a hydrothermal synthesis without the use of hydrogen fluoride (HF) and in the absence of any FAU zeolite Y. A gel composition formed upon using this method includes one or more sources of silica; one or more sources of alumina, one or more organic structure directing agents (OSDA); a source of alkali metal ions; and water. This gel composition is defined by the molar ratios of: SiO2/AI2O3 16:1 to 100:1; M2O/SiO2 0.15:1 to 0.30:1; ROH/SiO2 0.05:1 to 0.20:1; and H2O/SiO2 5:1 to 20:1; wherein M is the alkali metal ion and R is an organic moiety derived from the OSDA. This gel composition, after reacting at a temperature between 135° C. to about 180° C. for 15 hours to 168 hours forms the crystalline AEI-type zeolite having a silica to alumina ratio (SiO2:AI2O3) that is greater than 8:1.
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