公开(公告)号：US12129182B2

公开(公告)日：2024-10-29

申请号：US17345121

申请日：2021-06-11

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  David Shepard ,  Jin Cho ,  Mila Bortun ,  Yunkui Li ,  Wei Wu ,  Jeffery Lachapelle

IPC: C01G25/00 ,  B82Y30/00 ,  B82Y40/00 ,  F01N3/10

CPC classification number: C01G25/006 ,  F01N3/101 ,  B82Y30/00 ,  B82Y40/00 ,  C01P2004/03 ,  C01P2004/45 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14

Abstract: A nanocrystal-sized cerium-zirconium mixed oxide material includes at least 30% by mass zirconium oxide; between 5% to 55% by mass cerium oxide; and a total of 25% or less by mass of at least one oxide of a rare earth metal selected from the group of lanthanum, neodymium, praseodymium, or yttrium. The nanocrystal-sized cerium-zirconium mixed oxide exhibits hierarchically ordered aggregates having a d50 particle size less than 1.5 μm and a total pore volume after calcination at a temperature of 600° C. or more that is at least 0.7 cm3/g with a fraction of pores between 2 nm to 10 nm being less than 15%. The nanocrystal-sized cerium-zirconium mixed oxide material is prepared using a co-precipitation method followed by milling the dried and calcined oxide material. The nanocrystal-sized cerium-zirconium mixed oxide material forms a particulate filter that may be used in an exhaust system arising from a gas or diesel engine.

公开(公告)号：US12060280B2

公开(公告)日：2024-08-13

申请号：US17271233

申请日：2019-08-23

Applicant: Pacific Industrial Development Corporation

Inventor： Yunkui Li ,  David Shepard ,  De Gao ,  Wei Wu ,  Jeffery Lachapelle ,  Geng Zhang

IPC: C01B39/48 ,  B01J29/76 ,  B01J35/02 ,  B01J35/10 ,  B01J35/50 ,  B01J35/61 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30

CPC classification number: C01B39/48 ,  B01J29/76 ,  B01J35/50 ,  B01J35/615 ,  B01J35/617 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/036 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30 ,  B01J2229/186 ,  C01P2004/61 ,  C01P2006/12

Abstract: A method of forming an AEI-type zeolite in a hydrothermal synthesis without the use of hydrogen fluoride (HF) and in the absence of any FAU zeolite Y. A gel composition formed upon using this method includes one or more sources of silica; one or more sources of alumina, one or more organic structure directing agents (OSDA); a source of alkali metal ions; and water. This gel composition is defined by the molar ratios of: SiO2/AI2O3 16:1 to 100:1; M2O/SiO2 0.15:1 to 0.30:1; ROH/SiO2 0.05:1 to 0.20:1; and H2O/SiO2 5:1 to 20:1; wherein M is the alkali metal ion and R is an organic moiety derived from the OSDA. This gel composition, after reacting at a temperature between 135° C. to about 180° C. for 15 hours to 168 hours forms the crystalline AEI-type zeolite having a silica to alumina ratio (SiO2:AI2O3) that is greater than 8:1.

公开(公告)号：US12021237B2

公开(公告)日：2024-06-25

申请号：US17210598

申请日：2021-03-24

Applicant: Pacific Industrial Development Corporation

Inventor： Shuang Gao ,  David Shepard ,  Yunkui Li ,  Anatoly Bortun

IPC: H01M4/62 ,  H01M10/0525 ,  H01M4/02

CPC classification number: H01M4/62 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/027

Abstract: A negative electrode for use in an electrochemical cell, such as a lithium-ion secondary battery that includes a positive electrode with an active material that acts as a cathode and a current collector; a negative electrode with an active material that acts as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the positive and negative electrodes. The negative electrode, includes an inorganic additive dispersed therein or applied as a coating thereon, the inorganic additive being in the form of one or more zeolites having a Si:Al ratio ranging from 1-50 that absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride that become present in the cell. One or more of the cells may be combined in a housing to form a lithium-ion secondary battery.

公开(公告)号：US11883804B2

公开(公告)日：2024-01-30

申请号：US17283584

申请日：2019-10-24

Applicant: Pacific Industrial Development Corporation

Inventor： De Gao ,  Yunkui Li ,  David Shepard ,  Jeffery Lachapelle ,  Wei Wu

IPC: B01J29/76 ,  B01D53/94 ,  B01J20/28 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30 ,  C01B39/48 ,  F01N3/20 ,  F01N3/28

CPC classification number: B01J29/76 ,  B01D53/9418 ,  B01J20/28045 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1023 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/10 ,  B01J37/30 ,  C01B39/48 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9202 ,  B01D2255/9207 ,  C01P2002/72 ,  F01N3/2066 ,  F01N3/2803 ,  F01N2330/30 ,  F01N2370/04

Abstract: A method of forming an SSZ-13 zeolite in a hydrothermal synthesis yields an SSZ-13 zeolite that exhibits a silica to alumina (SiO2:Al2O3) molar ratio (SAR) that is less than 16:1; has a morphology that includes one or more of cubic, spheroidal, or rhombic particles with a crystal size that is in the range of about 0.1 micrometer (μm) to 10 μm. This SSZ-13 also exhibits a Brönsted acidity that is in the range of 2.0 mmol/g to 3.4 mmol/g as measured by ammonia temperature programmed desorption. A catalyst formed by substituting a metal into the framework of the zeolite provides for low temperature light-off of the NOx conversion reactions, while maintaining substantial performance at higher temperatures demonstrating hydrothermal stability.

公开(公告)号：US20210069680A1

公开(公告)日：2021-03-11

申请号：US16959460

申请日：2019-01-07

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  Mila Bortun ,  David Shepard ,  Yunkui Li ,  Jin Cho ,  Wei Wu ,  Jeffery Lachapelle

IPC: B01J23/83 ,  B01D53/94 ,  B01J37/03 ,  B01J37/06 ,  B01J37/04 ,  B01J37/08 ,  F01N3/10 ,  F01N3/28

Abstract: An oxygen storage material (OSM) that exhibits enhanced redox properties, developed mesoporosity, and a resistance to sintering. The oxygen storage material (OSM) has a high oxygen storage capacity (i.e., OSC>1.5 mmol H2/g) and enhanced reducibility (i.e., bimodal TPR-H2 profile with two Tmax in the temperature range from 150° C. to 550° C.). The OSM is suitable for use as a catalyst and a catalyst support. The method of making the oxygen storage material comprises the preparation of a solution containing zirconium, cerium, rare earth and transition metal salts, followed by the co-precipitation of all constituent metal hydroxides with a base.

公开(公告)号：US12227428B2

公开(公告)日：2025-02-18

申请号：US17422770

申请日：2019-12-19

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  Jin Cho ,  Yunkui Li ,  David Shepard ,  Mila Bortun

IPC: C01G25/00 ,  B01D53/94 ,  F01N3/022 ,  F01N3/10 ,  F01N3/28

Abstract: A nanocrystal-sized cerium-zirconium-aluminum mixed oxide material includes at least 20% by mass zirconium oxide; between 5% to 55% by mass cerium oxide; between 5% to 60% by mass aluminum oxide; and a total of 25% or less by mass of at least one oxide of a rare earth metal selected from the group of lanthanum, neodymium, praseodymium, or yttrium. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide exhibits hierarchically ordered aggregates having a dso particle size less than 1.5 μm, and retains at least 80% of surface area and pore volume after ageing at temperature higher than 1000° C. for at least 6 hours. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide material is prepared using a co-precipitation method followed by milling the dried and calcined oxide material. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide material forms a particulate filter that may be used in an exhaust system arising from a gas or diesel engine.

公开(公告)号：US20220393179A1

公开(公告)日：2022-12-08

申请号：US17770105

申请日：2020-10-30

Applicant: Pacific Industrial Development Corporation

Inventor： Shuang Gao ,  David Shepard ,  Yunkui Li ,  Anatoly Bortun

IPC: H01M4/62 ,  H01M50/446 ,  H01M10/0567 ,  H01M10/0525 ,  H01M50/124 ,  H01M50/451 ,  H01M50/414

Abstract: A cell for use in an electrochemical cell, such as a lithium-ion secondary battery that includes a positive electrode with an active material that acts as a cathode and a current collector; a negative electrode with an active material that acts as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the positive and negative electrodes. At least one of the cathode, the anode, the electrolyte, and the separator includes an inorganic additive in the form of a transition phase alumina or a type of boehmite that absorbs one or more of moisture and/or hydrogen fluoride (HF) that become present in the cell. One or more cells may be combined in a housing to form a lithium-ion secondary battery. The inorganic additive may also be incorporated as a coating applied to the internal wall of the housing.

公开(公告)号：US20220064017A1

公开(公告)日：2022-03-03

申请号：US17422770

申请日：2019-12-19

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  Jin Cho ,  Yunkui Li ,  David Shepard ,  Mila Bortun

IPC: C01G25/00 ,  B01D53/94 ,  F01N3/022 ,  F01N3/10 ,  F01N3/28

Abstract: A nanocrystal-sized cerium-zirconium-aluminum mixed oxide material includes at least 20% by mass zirconium oxide; between 5% to 55% by mass cerium oxide; between 5% to 60% by mass aluminum oxide; and a total of 25% or less by mass of at least one oxide of a rare earth metal selected from the group of lanthanum, neodymium, praseodymium, or yttrium. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide exhibits hierarchically ordered aggregates having a dso particle size less than 1.5 μm, and retains at least 80% of surface area and pore volume after ageing at temperature higher than 1000° C. for at least 6 hours. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide material is prepared using a co-precipitation method followed by milling the dried and calcined oxide material. The nanocrystal-sized cerium-zirconium-aluminum mixed oxide material forms a particulate filter that may be used in an exhaust system arising from a gas or diesel engine

公开(公告)号：US11224863B2

公开(公告)日：2022-01-18

申请号：US16959460

申请日：2019-01-07

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  Mila Bortun ,  David Shepard ,  Yunkui Li ,  Jin Cho ,  Wei Wu ,  Jeffery Lachapelle

IPC: B01D53/94 ,  B01J23/83 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  F01N3/10 ,  F01N3/28

Abstract: An oxygen storage material (OSM) that exhibits enhanced redox properties, developed mesoporosity, and a resistance to sintering. The oxygen storage material (OSM) has a high oxygen storage capacity (i.e., OSC>1.5 mmol H2/g) and enhanced reducibility (i.e., bimodal TPR-H2 profile with two Tmax in the temperature range from 150° C. to 550° C.). The OSM is suitable for use as a catalyst and a catalyst support. The method of making the oxygen storage material comprises the preparation of a solution containing zirconium, cerium, rare earth and transition metal salts, followed by the co-precipitation of all constituent metal hydroxides with a base.

公开(公告)号：US20210273293A1

公开(公告)日：2021-09-02

申请号：US17278685

申请日：2020-10-30

Applicant: Pacific Industrial Development Corporation

Inventor： Shuang Gao ,  David Shepard ,  Yunkui Li ,  Anatoly Bortun

IPC: H01M50/431 ,  H01M4/62 ,  H01M50/449 ,  H01M10/0525

Abstract: A cell for use in an electrochemical cell, such as a lithium-ion secondary battery that includes a positive electrode with an active material that acts as a cathode and a current collector; a negative electrode with an active material that acts as an anode and a current collector; a non-aqueous electrolyte; and a separator placed between the positive and negative electrodes. At least one of the cathode, the anode, the electrolyte, and the separator includes an inorganic additive in the form of one or more zeolites having a Si:Al ratio ranging from 2-50 that absorbs one or more of moisture, free transition metal ions, or hydrogen fluoride that become present in the cell. One or more of the cells may be combined in a housing to form a lithium-ion secondary battery. The inorganic additive may also be incorporated as a coating applied to the internal wall of the housing.