Invention Application
- Patent Title: A Method of Functionalizing Fluorinated Polymers, a Functionalized Fluorinated Polymer and Coating Compositions Thereof
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Application No.: US17767066Application Date: 2020-11-06
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Publication No.: US20220372193A1Publication Date: 2022-11-24
- Inventor: Frans A. Audenaert , Klaus Hintzer , Alain G. Verschuere
- Applicant: 3M INNOVATIVE PROPERTIES COMPANY
- Applicant Address: US MN St. Paul
- Assignee: 3M INNOVATIVE PROPERTIES COMPANY
- Current Assignee: 3M INNOVATIVE PROPERTIES COMPANY
- Current Assignee Address: US MN St. Paul
- International Application: PCT/IB2020/060462 WO 20201106
- Main IPC: C08F259/08
- IPC: C08F259/08 ; C09D151/00 ; C09D7/20 ; C09D7/40

Abstract:
Described herein is method of functionalizing fluorinated polymers, wherein a reaction compound is grafted onto a fluorinated polymer, wherein the fluorinated polymer comprises at least one Br, I, and Cl group and is free of —CH2CH2— linkages. In one embodiment, the functionalized fluorinated polymer comprises a perfluorinated polymer backbone with pendent groups therefrom is disclosed, wherein at least one pendent group is according to formula I: where Rf is a bond, or a divalent perfluorinated group, optionally comprising at least one in-chain ether linkage; Z is I, Br, or Cl; and X comprises a functional group selected from the group consisting of an alcohol; phosphorous acid and salts thereof; phosphoric acid and salts thereof; a silane; an amine; an amide; a hydrocarbon, optionally comprising an in-chain oxygen, nitrogen, or sulfur linkage; a carboxylic acid and salts thereof; an ester; a sulfonyl fluoride, a sulfonic acid and salts thereof; and combinations thereof. Such functionalized fluorinated polymers may be used in coating compositions.
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