发明授权
- 专利标题: Hydrogenation of hydrocarbons with catalytic microspheres
- 专利标题(中): 碳氢化合物与催化微球的氢化反应
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申请号: US3622500D申请日: 1970-04-21
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公开(公告)号: US3622500A公开(公告)日: 1971-11-23
- 发明人: ALPERT SEYMOUR B , CHERVENAK MICHAEL C , WOLK RONALD H
- 申请人: HYDROCARBON RESEARCH INC
- 专利权人: Hydrocarbon Research Inc
- 当前专利权人: Hydrocarbon Research Inc
- 优先权: US3043170 1970-04-21
- 主分类号: B01J8/22
- IPC分类号: B01J8/22 ; C10G47/12 ; C10G47/28 ; C10G49/02 ; C10G13/02 ; C10G13/18
摘要:
Hydrocarbon fractions boiling below 975* F. are obtained by hydrocracking heavy hydrocarbon oils, containing 40-100 percent by volume of hydrocarbon fractions boiling above 975* F., in the liquid state in the presence of ebullated catalytic macroporous microspheres. These microspheres are smaller than 60 mesh (U.S. Standard) and larger than 325 mesh. They have a pore volume of at least 0.10 cc./g. in pores larger than 250 Angstroms (A) and at least 0.30 cc./g. in pores less than 250 A. The macroporous, microspheres have an average size such that 80 weight percent fall within a narrow size range and are ebullated by the upward flow of oil and hydrogen through the reactor during hydroconversion. The pore volume of the microspheres is critical as there must be a penetration of the hydrocarbon oil into the catalyst for at least a 3 percent gain in weight.
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