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    Hydrocracking and desulfurization with a catalyst having
    1.
    发明授权
    Hydrocracking and desulfurization with a catalyst having 失效
    具有催化剂的水解和脱硫

    公开(公告)号：US3630888A

    公开(公告)日：1971-12-28

    申请号：US3630888D

    申请日：1970-03-02

    Applicant: HYDROCARBON RESEARCH INC

    Inventor： ALPERT SEYMOUR B ,  WOLK RONALD H ,  MARUHNIC PETER ,  CHERVENAK MICHAEL C

    IPC: B01J37/00 ,  C10G49/04 ,  C10G23/02 ,  C10G13/02

    CPC classification number: B01J37/0018 ,  C10G2300/107

    Abstract: A PROCESS FOR CARRYING OUT CATALYTIC REACTIONS, SUCH AS, HYDROGENATION, DESULFURIZATION, HYDROCRACKING, INCLUDING HALOGENTAION, OXIDATION, SULFONATIN, NITRATION, AND AMIDIZATION OF HYDROCARBONS OR THE LIKE IN FIXED, SLURRIED, FLUIDIZED, AND EBULLATED BEDS UTILIZING A CATALYST HAVING MICOROPORES AND ACCESS CHANNEL; AND WHEREIN THE ACCESS CHANNELS ARE INTERSTITALLY SPACED THROUGOUT THE MICROPORES; AND WHEREIN 10 TO 40% OF THE TOTAL PORE VOLUME IS COMPOSED OF ACCESS CHANNELS HAVNG DIAMETERS GREATER THAN 1000 ANGSTROMS; AND WHEREIN 10 TO 40% OF THE TOTAL PORE VOLUME IS COMPOSED OF ACCESS CHANNELS HAVING DIAM-

    ETERS BETWEEN ABOUT 100 AND 1000 ANGSTROMS; AND WHEREIN THESE ACCESS CHANNELS ARE SUBSTANTIALLY UNIFORM AS TO THEIR PARAMETERS AND ARE RELATIVELY STRAIGHT WITH MINUMUM BENDING AND CONSTRICTION; AND WHEREIN THE REMAINDER OF THE CATALYST PORE VOLUME COMPRISES MICROPORES WITH DIAMETERS LESS THAN 100 ANGSTROMS WITH THE REAMINDER BEING 20 TO 80% OF THE TOTAL PORE VOLUME. METHODS FOR PREPARING THIS CATALYST WITH RESPECT OT ORIENTATION OF THE ACCESS CHANNELS ARE DESCRIBED.

    Higher conversion hydrogenation
    2.
    发明授权
    Higher conversion hydrogenation 失效
    高转换加氢

    公开(公告)号：US3681231A

    公开(公告)日：1972-08-01

    申请号：US3681231D

    申请日：1971-02-10

    Applicant: HYDROCARBON RESEARCH INC

    Inventor： ALPERT SEYMOUR B ,  WOLK RONALD H ,  CHERVENAK MICHAEL C

    IPC: C10G49/12 ,  C10G9/16 ,  C10G13/02 ,  C10G37/04 ,  C23F14/00

    CPC classification number: C10G49/12

    Abstract: A PROCESS FOR THE HYDROGENATION OF A PETROLEUM RESIDUUM FEED MATERIAL CONTAINING AT LEAST 25 VOLUME PERCENT MATERIAL BOILING ABOVE 975*F. AND GREATER THAN 5 WEIGHT PERCENT ASPHALTENES BY REACTING THE FEED WITH A HYDROGEN RICH GAS AT ELEVATED TEMPERATURES AND PRESSURES IN AN EBULLATED CATALYTIC BED REACTOR WHEREIN SAID FEED MATERIAL IS BLENDED WITH AN AROMATIC DILUENT HAVING A GRAVITY OF LESS THAN 16* APL, A WATSON CHARACTERIZATION FACTOR OF LESS THAN 11.2 AND A BOILING POINT WITHIN THE RANGE OF FROM ABOUT 700*F. TO ABOUT 1000*F., PRIOR TO HYDROGENATION.

    Coal hydrogenation
    3.
    发明授权
    Coal hydrogenation 失效
    煤矿加氢

    公开(公告)号：US3617465A

    公开(公告)日：1971-11-02

    申请号：US3617465D

    申请日：1969-11-20

    Applicant: HYDROCARBON RESEARCH INC

    Inventor： WOLK RONALD H ,  JOHANSON EDWIN S ,  ALPERT SEYMOUR B

    IPC: C10G1/06

    CPC classification number: C10G1/065

    Abstract: A coal hydrogenation process employing an expanded particulate solids bed wherein the solids are derived from the coal which is placed in random motion by the upflow of a slurry of coal, hydrocarbon liquid and hydrogen to produce better than 80 percent conversion of coal to gas and liquid synthetic petroleum products. The particulate solids bed is derived from the coal being fed to the reaction zone.

    Hydroconversion process of residuum oils
    4.
    发明授权
    Hydroconversion process of residuum oils 失效
    残油的氢化反应过程

    公开(公告)号：US3870623A

    公开(公告)日：1975-03-11

    申请号：US39707173

    申请日：1973-09-13

    Applicant: HYDROCARBON RESEARCH INC

    Inventor： JOHNSON AXEL R ,  WOLK RONALD H ,  ALPERT SEYMOUR B

    IPC: C10G45/16 ,  C10G13/02 ,  B01J11/74 ,  C10G9/16

    CPC classification number: C10G45/16

    Abstract: In processing high metals Venezuelan residuum, higher conversion of the 975*F plus fraction and improved operability can be obtained by maintaining a high catalyst addition rate to obtain reduced metals loading on the catalyst; it being determined that for a macroporous catalyst there is a limiting factor of metals deposition.

    Abstract translation: 在处理高金属委内瑞拉残渣中，通过保持高催化剂加入速率可获得975°F加馏分的较高转化率和改进的可操作性，以获得催化剂上的还原金属负载量; 确定对于大孔催化剂，存在金属沉积的限制因素。

    Hydroconversion of waste natural and synthetic rubbers
    5.
    发明授权
    Hydroconversion of waste natural and synthetic rubbers 失效
    废水自然和合成橡胶的降解

    公开(公告)号：US3704108A

    公开(公告)日：1972-11-28

    申请号：US3704108D

    申请日：1970-09-25

    Applicant: HYDROCARBON RESEARCH INC

    Inventor： ALPERT SEYMOUR B

    IPC: B29B17/00 ,  C10G1/10 ,  C10L1/16

    CPC classification number: C10G1/10

    Abstract: WASTE NATURAL AND SYNTHETIC RUBBERS ARE CONVERTED IN THE PRESENCE OF A CATALYST AND IN A HYDROGEN ENVIRONMENT BY PASSING A PARTICULATE RUBBER SLURRY AND HYDROGEN UPWARDLY THROUGH A REACTOR MAINTAINED UNDER TEMPERATURES IN THE 700 TO 850* F. RANGE AND PRESSURES IN THE 500 TO 3000 P.S.I.G. RANGE. THE PARTICULATE RUBBER IS CONVERTED IN THE REACTOR TO HYDROCARBON LIQUIDS WHILE UNCONVERTIBLE SOLIDS ORIGINALLY COMPOUNDED WITH THE RUBBER LEAVE UNCHANGED IN THE PRODUCT. THE HYDROCARBON STREAM CAN HAVE A WIDE RANGE OF PROPERTIES DEPENDING ON THE OBJECTIVES OF THE USER OF THE PROCESS.

    Hydrogenation of hydrocarbons with catalytic microspheres
    8.
    发明授权
    Hydrogenation of hydrocarbons with catalytic microspheres 失效
    碳氢化合物与催化微球的氢化反应

    公开(公告)号：US3622500A

    公开(公告)日：1971-11-23

    申请号：US3622500D

    申请日：1970-04-21

    Applicant: HYDROCARBON RESEARCH INC

    Inventor： ALPERT SEYMOUR B ,  CHERVENAK MICHAEL C ,  WOLK RONALD H

    IPC: B01J8/22 ,  C10G47/12 ,  C10G47/28 ,  C10G49/02 ,  C10G13/02 ,  C10G13/18

    CPC classification number: C10G49/02 ,  B01J8/22 ,  C10G47/12 ,  C10G47/28

    Abstract: Hydrocarbon fractions boiling below 975* F. are obtained by hydrocracking heavy hydrocarbon oils, containing 40-100 percent by volume of hydrocarbon fractions boiling above 975* F., in the liquid state in the presence of ebullated catalytic macroporous microspheres. These microspheres are smaller than 60 mesh (U.S. Standard) and larger than 325 mesh. They have a pore volume of at least 0.10 cc./g. in pores larger than 250 Angstroms (A) and at least 0.30 cc./g. in pores less than 250 A. The macroporous, microspheres have an average size such that 80 weight percent fall within a narrow size range and are ebullated by the upward flow of oil and hydrogen through the reactor during hydroconversion. The pore volume of the microspheres is critical as there must be a penetration of the hydrocarbon oil into the catalyst for at least a 3 percent gain in weight.

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