发明授权
US3876725A Antistatic fiber containing chain-extended tetrols based on diamines
失效
基于DIAMINES的包含链条延伸片的抗静电纤维
- 专利标题: Antistatic fiber containing chain-extended tetrols based on diamines
- 专利标题(中): 基于DIAMINES的包含链条延伸片的抗静电纤维
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申请号: US46877174申请日: 1974-05-10
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公开(公告)号: US3876725A公开(公告)日: 1975-04-08
- 发明人: WELLS RODNEY LEE , CRESCENTINI LAMBERTO
- 申请人: ALLIED CHEM
- 专利权人: Allied Corp
- 当前专利权人: Allied Corp
- 优先权: US46877174 1974-05-10; US34119473 1973-03-14
- 主分类号: C08K5/13
- IPC分类号: C08K5/13 ; C08G41/04
摘要:
It has been suggested that antistatic properties of fibers of polyamide could be improved by uniformly dispersing in the polyamide between about 1 percent and about 12 percent by weight of a predominantly branched, chain-extended propylene oxideethylene oxide copolymer based on a diamine. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of "nubs" or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer about 0.5 to 12 percent by weight, based on the weight of the antistatic agent, of a phenol compound represented by the formula:
where R is an alkyl hydrocarbon group containing less than nine carbon atoms and R.sub.1 is a tertiary alkyl group containing at least four but not more than 12 carbon atoms. In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.
where R is an alkyl hydrocarbon group containing less than nine carbon atoms and R.sub.1 is a tertiary alkyl group containing at least four but not more than 12 carbon atoms. In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.
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