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1.发明授权
公开(公告)号：US3876725A
公开(公告)日：1975-04-08
申请号：US46877174
申请日：1974-05-10
申请人： ALLIED CHEM
摘要： It has been suggested that antistatic properties of fibers of polyamide could be improved by uniformly dispersing in the polyamide between about 1 percent and about 12 percent by weight of a predominantly branched, chain-extended propylene oxideethylene oxide copolymer based on a diamine. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of "nubs" or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer about 0.5 to 12 percent by weight, based on the weight of the antistatic agent, of a phenol compound represented by the formula:
where R is an alkyl hydrocarbon group containing less than nine carbon atoms and R.sub.1 is a tertiary alkyl group containing at least four but not more than 12 carbon atoms. In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.-
2.发明授权
公开(公告)号：US3873639A
公开(公告)日：1975-03-25
申请号：US27131672
申请日：1972-07-12
申请人： ALLIED CHEM
CPC分类号： C08L77/00 , Y10S524/905 , C08L2666/20
摘要： WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6 IS ADDED.
IN WHICH R is
IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
AN ADDITIONAL SMALL PROPORTION OF A HINDERED PHENOL REPRESENTED BY THE FORMULAE:
AND AT LEAST ONE COMPOUND SELECTED FROM THE GROUP CONSISTING OF DIEPOXIDES AND COMPOUNDS WHICH YIELD THE FOLLOWING DIVALENT RADICALS:
A antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:摘要翻译： 聚酰胺纤维的抗静电性能可以通过在聚酰胺中分散一小部分由下式表示的四元醇化合物的反应产物来改善：
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公开(公告)号：US3917449A
公开(公告)日：1975-11-04
申请号：US44159574
申请日：1974-02-11
申请人： ALLIED CHEM
CPC分类号： D06P3/24 , D06P1/5285 , Y10S8/924 , Y10S8/929 , Y10T442/2557
摘要： When from about 0.5 percent to about 5 percent of a polythiourea is coated on nylon fiber an improved dye fastness is achieved compared to untreated dyed nylon fiber when this fiber is exposed to ozone.
摘要翻译： 当约0.5％至约5％的聚硫脲涂覆在尼龙纤维上时，与未经处理的染色尼龙纤维相比，当该纤维暴露于臭氧时，获得了改进的染色牢度。
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公开(公告)号：US3882190A
公开(公告)日：1975-05-06
申请号：US40887373
申请日：1973-10-23
申请人： ALLIED CHEM
发明人： WELLS RODNEY LEE
CPC分类号： C08K5/13 , C08L71/00 , C08L77/00 , Y10S524/91 , C08L2666/20
摘要： An improved antistatic polyamide fiber is prepared by incorporating in the fiber about 1 to 12 percent by weight of a chain-extended propylene oxide-ethylene oxide copolymer based on ethylene diamine and about 0.5 to 8 percent by weight of a phenol compound represented by the formula:
WHERE R1 is hydrogen or an alkyl radical containing 1 to 12 carbon atoms, R2 is an alkyl radical containing 4 to 18 carbon atoms, and R3 is an alkyl radical containing 4 to 18 carbon atoms. A typical preferred chain-extended agent is 4,4''methylene-bis-(cyclohexyl isocyanate).-
公开(公告)号：US3859380A
公开(公告)日：1975-01-07
申请号：US44304874
申请日：1974-02-15
申请人： ALLIED CHEM
CPC分类号： C08K5/1345 , C08L77/00 , D01F1/09 , Y10S524/905 , C08L2666/20
摘要： IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
IN WHICH A is
WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6.
WHERE R10 is a divalent radical having 1 to 20 carbon atoms derived from aliphatic, aromatic, cycloaliphatic, aromaticaliphatic, or heterocyclic hydrocarbons. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulas:
WHERE R6, R7, R8 and R9 are independently selected from R1, R2, R3, R4 or another monovalent hydrocarbon radical having 1 to 20 carbon atoms as defined for R1, R2, R3 and R4, provided that at least one of R1, R2, R3, R4, R5, R6, R7, R8 or R9 is R''; where n is 3 to 6, r and u are 2, 3, or 4; m, q are 0 to 100; m + q must be >5; w is 2, 3, or 4; p is 2 or 3; f, g, are 0 or 2 to 6; s and t are 0 or a whole number and s + t must be less than 100; a and b are whole numbers; D. the reaction product of A, B and/or C with at least one compound selected from I. DIEPOXIDES, AND II. COMPOUNDS WHICH YIELD THE FOLLOWING DIVALENT RADICALS
R1, R2, R3 and R4 are independently selected from R'' and monovalent hydrocarbon radicals having 1 to 20 carbon atoms derived from aliphatic, aromatic, cycloaliphatic, aromaticaliphatic, heterocyclic hydrocarbons or -(CrH2rO)m(CpH2pO)q-H; R5 is ethylene radical, R or a divalent radical selected from:
AND -(CrH2rO)s-(CuH2uO)t-CwH2w-; where R'', R'''', R'''''' and R'''''''' are
WHERE R is at least one of the alkylene difunctional radicals having 3 to 15 carbon atoms and a radical selected from
It has been suggested that an antistatic fiber of polyamide can be prepared by uniformly dispersing in the polymer a small proportion of at least one compound having a molecular weight above 1500 selected from the group consisting of compounds represented by the formulas:-
6.发明授权
公开(公告)号：US3923924A
公开(公告)日：1975-12-02
申请号：US52799574
申请日：1974-11-29
申请人： ALLIED CHEM
CPC分类号： C08K5/13 , C08L77/00 , Y10S524/913 , C08L2666/20
摘要： It has been suggested that antistatic properties of fibers of polyamide could be improved by uniformly dispersing in the polyamide between about 1 percent and about 12 percent by weight of a predominantly branched, chain-extended propylene oxideethylene oxide copolymer based on a diamine. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in melt-spinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer about 0.5 to 12% by weight, based on the weight of the antistatic agent, of a phenol compound represented by the formula:
In comparative tests with antistatic yarns containing various commercially available hindered phenol compounds, the yarns of the present invention showed significantly greater breaking strength retention after exposure to light in standard tests.摘要翻译： 已经提出通过在聚酰胺中均匀分散在基于二胺的占主要分支的，链延长的环氧丙烷 - 环氧乙烷共聚物的约1重量％和约12重量％之间来改善聚酰胺纤维的抗静电性能。 然而，通过在聚酰胺中并入该抗静电添加剂，由于在挤出的聚酰胺长丝中频繁出现“凸点”或扩大位置，在熔纺中遇到严重的问题。 现在已经发现，通过在聚合物中分散约0.5-12重量％（以抗静电剂的重量计），由式（I）表示的酚化合物分散在抗静电聚酰胺纤维中， ：其中R是含有少于9个碳原子的烷基烃基，R 1是含有至少4个但不多于12个碳原子的叔烷基。
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公开(公告)号：US3888944A
公开(公告)日：1975-06-10
申请号：US49442374
申请日：1974-08-05
申请人： ALLIED CHEM
CPC分类号： C08L77/00 , Y10S260/17 , Y10S260/21 , Y10S524/905 , C08L2666/20
摘要： It has been suggested that antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:
WHERE A'' is a difunctional radical from a hydrocarbon containing 1 to 30 carbon atoms. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in meltspinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulae:
IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
IN WHICH R is
WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6. When the term ''''alkyl'''' is qualified by the designation ''''(lower)'''', there is intended a branched or straight chain hydrocarbon of from 1 to about 6 carbon atoms. Preferably, the phenol complound is used with at least 0.1% by weight, based on the weight of the antistatic additive, of a sulfur compound of the formula:
WHEREIN R'''' is an alkyl radical containing 8 to 18 carbon atoms and n is 1 to 3.
WHERE A, B, C, D, E, F, G, AND H ARE EACH A WHOLE NUMBER AND A is a difunctional radical from a hydrocarbon containing 1 to 13 carbon atoms, said tetrol compound having a molecular weight between about 4,000 and about 50,000, and at least one compound selected from the group consisting of diepoxides and compounds which yield the following divalent radicals:-
公开(公告)号：US3887644A
公开(公告)日：1975-06-03
申请号：US40768073
申请日：1973-10-18
申请人： ALLIED CHEM
发明人： WELLS RODNEY LEE
CPC分类号： C08L77/00 , C08K5/13 , C08L71/02 , C08L2666/20
摘要： An improved antistatic polyamide fiber is prepared by incorporating in the fiber about 1 to 12 percent by weight of a chain-extended propylene oxide-ethylene oxide copolymer based on ethylene diamine and about 0.5 to 8 percent by weight of a phenol compound represented by the formula:
WHERE R1 is hydrogen or an alkyl radical containing 1 to 12 carbon atoms, R2 is an alkyl radical containing 4 to 18 carbon atoms, and R3 is an alkyl radical containing 4 to 18 carbon atoms. The preferred chain-extending agent is dimethyl terephthalate.摘要翻译： 改进的抗静电聚酰胺纤维是通过在纤维中加入约1至12重量％的基于乙二胺的延伸链环氧丙烷 - 环氧乙烷共聚物和约0.5-8重量％由式 ：
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9.发明授权
公开(公告)号：US3887638A
公开(公告)日：1975-06-03
申请号：US49442174
申请日：1974-08-05
申请人： ALLIED CHEM
CPC分类号： C08K5/1345 , C08L77/00 , Y10S260/17 , Y10S260/21 , Y10S524/913 , C08L2666/20
摘要： It has been suggested that antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:
WHERE A, B, C, D, E, F, G, AND H ARE EACH A WHOLE NUMBER AND A is a difunctional radical from a hydrocarbon containing 1 to 13 carbon atoms, said tetrol compound having a molecular weight between about 4,000 and about 50,000, and at least one compound selected from the group consisting of diepoxides and compounds which yield the following divalent radicals:
WHERE A'' is a difunctional radical from a hydrocarbon containing 1 to 30 carbon atoms. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in meltspinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulae:
IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND
IN WHICH R is
WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6. When the term ''''alkyl'''' is qualified by the designation ''''(lower),'''' there is intended a branched or straight chain hydrocarbon of from 1 to about 6 carbon atoms. Preferably, the phenol compound is used with at least 0.1% by weight, based on the weight of the antistatic additive, of a sulfur compound of the formula:
WHEREIN R'''' is an alkyl radical containing 8 to 18 carbon atoms and n is 1 to 3.摘要翻译： 已经提出通过在聚酰胺中分散一小部分由下式表示的四元醇化合物的反应产物可以提高聚酰胺纤维的抗静电性能：
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