发明授权
- 专利标题: Manufacture of aliphatic alcohols
- 专利标题(中): 脂肪醇的制造
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申请号: US41807073申请日: 1973-11-21
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公开(公告)号: US3880940A公开(公告)日: 1975-04-29
- 发明人: BAER KARL , ELLIEHAUSEN HEINRICH , HOHENSCHUTZ HEINZ , STROHMEYER MAX , ZIRKER GUENTER
- 申请人: BASF AG
- 专利权人: Basf Ag
- 当前专利权人: Basf Ag
- 优先权: DE2257673 1972-11-24
- 主分类号: C07C29/14
- IPC分类号: C07C29/14 ; B01J23/00 ; B01J23/883 ; C07B61/00 ; C07C27/00 ; C07C29/141 ; C07C31/02 ; C07C67/00
摘要:
Manufacture of saturated aliphatic alcohols by hydrogenation of saturated aliphatic aldehydes at temperatures of from 140* to 230*C at pressures of from 50 to 350 atmospheres in the presence of catalysts containing from 5 to 15% by weight nickel and 5 to 20% by weight molybdenum supported on silicic acid, in which process catalysts are used which have been obtained by heating silicic acid carrier materials to temperatures of from 700* to 1200*C, impregnating the resulting silicic acid carrier materials with nickel and molybdenum salts, drying the resulting material with or without further heating to temperatures of from 200* to 500*C and subsequently treating the product with hydrogen at elevated temperature in conventional manner. The alcohols obtained are used as solvents or for the manufacture of plasticizers for polyvinyl chloride.
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