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公开(公告)号：US3520937A
公开(公告)日：1970-07-21
申请号：US3520937D
申请日：1967-04-03
申请人： BASF AG
发明人： MOELL HANS , ECKERT ERNST , KERBER HORST , APPL MAX , HOHENSCHUTZ HEINZ , WALZ HELMUT
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公开(公告)号：US3880940A
公开(公告)日：1975-04-29
申请号：US41807073
申请日：1973-11-21
申请人： BASF AG
IPC分类号： C07C29/14 , B01J23/00 , B01J23/883 , C07B61/00 , C07C27/00 , C07C29/141 , C07C31/02 , C07C67/00
CPC分类号： B01J23/883 , C07C29/141 , C07C31/12
摘要： Manufacture of saturated aliphatic alcohols by hydrogenation of saturated aliphatic aldehydes at temperatures of from 140* to 230*C at pressures of from 50 to 350 atmospheres in the presence of catalysts containing from 5 to 15% by weight nickel and 5 to 20% by weight molybdenum supported on silicic acid, in which process catalysts are used which have been obtained by heating silicic acid carrier materials to temperatures of from 700* to 1200*C, impregnating the resulting silicic acid carrier materials with nickel and molybdenum salts, drying the resulting material with or without further heating to temperatures of from 200* to 500*C and subsequently treating the product with hydrogen at elevated temperature in conventional manner. The alcohols obtained are used as solvents or for the manufacture of plasticizers for polyvinyl chloride.
摘要翻译： 在含有5至15重量％镍和5至20重量％催化剂的催化剂存在下，通过在140至230℃的温度下，在50至350大气压的压力下，饱和脂族醛的氢化制备饱和脂族醇 负载在硅酸上的钼，其中使用通过将硅酸载体材料加热至700℃至1200℃的温度而获得的工艺催化剂，用镍和钼盐浸渍所得硅酸载体材料，干燥所得材料 有或没有进一步加热至200℃至500℃的温度，随后以常规方式在升高的温度下用氢处理产物。 所得的醇用作溶剂或制造聚氯乙烯的增塑剂。
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公开(公告)号：US3880923A
公开(公告)日：1975-04-29
申请号：US42637273
申请日：1973-12-19
申请人： BASF AG
摘要： An improved process for the production of Alpha chlorocarboxylic acid chlorides by reaction of a carboxylic acid chloride with chlorine at elevated temperature, wherein the improvement consists in carrying out the reaction in the presence of sulfuric acid. Alpha -chlorocarboxylic acid chlorides are suitable for the production of plant protection agents.
摘要翻译： 通过羧酸酰氯与氯在升高的温度下反应制备α-氯代羧酸氯化物的改进方法，其中改进在于在硫酸存在下进行反应。 α-氯代羧酸氯化物适用于生产植物保护剂。
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公开(公告)号：US3929898A
公开(公告)日：1975-12-30
申请号：US27693672
申请日：1972-08-01
申请人： BASF AG
摘要： A process for the production of mainly linear aldehydes by hydroformylation of an olefinically unsaturated compound of from two to twenty carbon atoms with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of a cobalt carbonyl complex prepared prior to the hydroformylation from an aqueous solution of a cobalt salt, wherein in a first stage an aqueous solution of a cobalt salt is treated with carbon monoxide and hydrogen at a temperature of from 50* to 200*C and at a pressure of from 100 to 400 atmospheres in the presence of activated carbon, a zeolite or a basic ion exchanger which has been loaded with cobalt carbonyl, the aqueous solution containing cobalt salt and cobalt carbonyl hydride thus obtained and the mixture of carbon monoxide and hydrogen, without releasing the pressure, are extracted at a temperature of 20* to 100*C and at a pressure of 100 to 400 atmospheres in a second stage with a saturated hydrocarbon or the olefinically unsaturated compound used for the hydroformylation (provided they are insoluble in water and liquid under the conditions used), water-insoluble oxo reaction product or hydrogenated oxo reaction product, the aqueous phase is separated and the organic phase containing the carbonyl complex thus obtained and the mixture of carbon monoxide and hydrogen are transferred to a third stage and, after supplying olefinically unsaturated compound (if this has not been used or has only partly been used for extraction in the abovementioned stage) hydroformylation is carried out at a temperature of from 70* to 170*C and a pressure of from 100 to 400 atmospheres. The products of the process are suitable for the production of detergent alcohols and plasticizers and for the production of carboxylic acids and amines.
摘要翻译： 通过在二氧化碳和氢气的烯属不饱和化合物与一氧化碳和氢气在升高的温度和超大气压下，在羰基化羰基络合物存在下，在氢化甲酰化之前，从水溶液中加氢甲酰化制备主要线性醛的方法 钴盐溶液，其中在第一阶段中钴盐的水溶液用一氧化碳和氢气在50至200℃的温度和100至400大气压的压力下在有 活性炭，已经负载有羰基钴的沸石或碱性离子交换剂，由此获得的含有钴盐和羰基氢化钴的水溶液和一氧化碳和氢气的混合物而不释放压力，在 20〜100℃，在100〜400个大气压的压力下，在第二阶段用饱和烃或硫酸 用于加氢甲酰化的烯属不饱和化合物（只要它们在所用条件下不溶于水和液体），水不溶性氧代反应产物或氢化羰基反应产物，分离水相，并将含有羰基络合物的有机相如此得到 将一氧化碳和氢气的混合物转移到第三阶段，在提供烯属不饱和化合物（如果没有使用或仅在上述阶段中仅部分用于萃取）之后，加氢甲酰化在 70〜170℃，压力为100〜400个大气压。
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5.发明授权Continuous production of esters of glycols or their monoethers with lower fatty acids 失效连续生产二醇或其单醚与低级脂肪酸的酯
公开(公告)号：US3923874A
公开(公告)日：1975-12-02
申请号：US36732773
申请日：1973-06-06
申请人： BASF AG
摘要： Continuous production of substantially or wholly water-soluble esters of glycols or their monoethers with lower fatty acids by reaction of a glycol of the formula (I): HO-A-X (I) in which A is ethylene, propylene or butylene; and X is OH or OR in which R is alkyl of one to four carbon atoms or OAOH or OAOR in which A and R have the meanings given above with a lower saturated fatty acid at elevated temperature in the presence of a catalytic amount of a strong acid while continuously removing the water formed by means of an entrainer followed by treatment with an aqueous alkali. The glycol of the formula (I) is reacted in a first zone with the lower fatty acid, the water formed being distilled off as an azeotrope over the top by means of an entrainer, and the crude glycol ester including the entrainer is removed from the bottoms, mixes with an aqueous alkali, extracted in a second zone while supplying an extractant and water with phase separation and in a third zone the pure glycol ester is recovered from the resulting mixture of glycol ester, entrainer and extractant by rectification. Glycol esters are used as solvents for surface coating agents.
摘要翻译： 通过式（I）的二元醇：其中A是乙烯，丙烯或丁烯的HO-A-X（I）的反应连续生产二醇或其单醚与低级脂肪酸的基本上或完全水溶性的酯; 并且X是OH或OR，其中R是1-4个碳原子的烷基或OAOH或OAOR，其中A和R在较高饱和脂肪酸中具有上述含义，在催化剂量的强度存在下， 同时连续除去通过夹带剂形成的水，然后用碱水溶液处理。 式（I）的二醇在第一区域与低级脂肪酸反应，形成的水通过夹带剂在顶部作为共沸物蒸馏出来，并将包含夹带剂的粗乙醇酯从 底部，与碱水溶液混合，在第二区域中提取，同时提供萃取剂和进行相分离的水，在第三区域，通过精馏从所得到的乙二醇酯，夹带剂和萃取剂的混合物中回收纯乙二醇酯。 乙二醇酯用作表面涂层剂的溶剂。
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公开(公告)号：US3627830A
公开(公告)日：1971-12-14
申请号：US3627830D
申请日：1969-02-03
申请人： BASF AG
发明人： KERBER HORST , HOHENSCHUTZ HEINZ , RAUCH KONRAD
IPC分类号： C08K5/20 , C07C103/00
CPC分类号： C08K5/20
摘要： Production of pure N-dimethylacylamides having from two to four carbon atoms in the acyl radical by reaction of an excess of dimethylamine with an aliphatic carboxylic acid having two to four carbon atoms at elevated temperature and distillation of the N-dimethylacylamide formed, the distillation being carried out continuously in a column. Dimethylamine and the carboxylic acid in the molar ratio from 1.1:1 to 5:1 are introduced at from 80* to 220* C. and from 0.1 to 2 atmospheres in the absence of any catalyst into a mixture of N-dimethylacylamide and its carboxylic acid, the carboxylic acid content of the mixture corresponding at least to the amount of carboxylic acid present in the azeotropic mixture of the N-dimethylacylamide and its carboxylic acid. Ndimethylacylamides are used as solvents for polymers.
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