发明授权
- 专利标题: Manufacture of copolymers of 4-methylpentene-1
- 专利标题(中): 4-甲基戊烯-1共聚物的制造
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申请号: US547636申请日: 1975-02-06
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公开(公告)号: US3969333A公开(公告)日: 1976-07-13
- 发明人: Johann Nickl , Hans Schick , Heinz Mueller-Tamm
- 申请人: Johann Nickl , Hans Schick , Heinz Mueller-Tamm
- 申请人地址: DT Ludwigshafen (Rhine)
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DT Ludwigshafen (Rhine)
- 主分类号: C08F4/00
- IPC分类号: C08F4/00 ; C08F4/60 ; C08F10/00 ; C08F10/14 ; C08F210/14 ; C08F2/38 ; C08F4/52 ; C08F210/00
摘要:
Copolymers of 4-methylpentene-1 are prepared by copolymerization of 4-methylpentene-1 with one or more other C.sub.2-18 .alpha.-alkenes at a temperature above room temperature and in the presence of hydrogen using a Ziegler/Natta catalyst system. The polymerization is carried out at a relatively very high temperature and in the presence of an inert gas with the proviso that the partial pressures of the inert gas and of the hydrogen and the sum of the partial pressures of the inert gas, hydrogen and 4-methylpentene-1 have specific values. In this way, copolymers having large crystalline fractions are obtained in a high yield per unit of catalyst system per unit time.