发明授权
- 专利标题: 2,4,6-Trialkyl L-3-hydroxyphenylalkanoates
- 专利标题(中): 2,4,6-三烷基L-3-羟基苯基链烷酸酯
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申请号: US494156申请日: 1974-08-02
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公开(公告)号: US3988363A公开(公告)日: 1976-10-26
- 发明人: John D. Spivack , Martin Dexter
- 申请人: John D. Spivack , Martin Dexter
- 申请人地址: NY Ardsley
- 专利权人: Ciba-Geigy Corporation
- 当前专利权人: Ciba-Geigy Corporation
- 当前专利权人地址: NY Ardsley
- 主分类号: C07C59/52
- IPC分类号: C07C59/52 ; C07C69/76 ; C07D295/18 ; C08K5/134 ; C08K5/20 ; C08L23/02 ; C08L25/10 ; C08L77/00 ; C10M133/16
摘要:
Ester and amides having the formula ##SPC1##Wherein R, R.sup.1 and R.sup.2 are independently lower alkyl or cycloalkyl groups, R.sup.3 is hydrogen, alkyl, cycloalkyl, alkylene, phenyl, phenyl substituted by alkyl groups, alkylthioethyl, thiobis-alkylene, alkyleneoxyalkylene, polyoxyalkylene or a polyvalent cyclic or acyclic hydrocarbon radical, R.sup.4 is hydrogen, lower alkyl, cycloalkyl, R.sup.5 is hydrogen, alkyl, phenyl, phenyl substituted by alkyl groups, alkylene, a polyvalent cyclic or acyclic hydrocarbon radical or alkyleneoxyalkylene, A is lower alkylene, m is 1 to 4 and n is 1 to 6.The esters are prepared by usual esterification procedures from a suitable alcohol and an acid of the formula III ##SPC2##or an acid halide or acid anhydride thereof. The higher alkyl esters can also be prepared from the lower alkyl ester, especially the methyl ester, by transesterification with a higher alkanol or polyol.The amides are prepared by usual amidation procedures by reacting a carboxylic acid of formula III, an acid chloride, anhydride or a lower alkyl ester thereof with the appropriate amine.The nitriles corresponding to acids of formula III are prepared as well as some malonate esters derived having the formula V. ##SPC3##The compounds are useful as stabilizers or organic materials, especially polyolefins, which deteriorate upon exposure to light and heat.
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