发明授权
US4108814A Aqueous polyurethane dispersions from solvent-free prepolymers using
sulfonate diols
失效
使用磺酸二醇的无溶剂预聚物的水性聚氨酯分散体
- 专利标题: Aqueous polyurethane dispersions from solvent-free prepolymers using sulfonate diols
- 专利标题(中): 使用磺酸二醇的无溶剂预聚物的水性聚氨酯分散体
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申请号: US777206申请日: 1977-03-14
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公开(公告)号: US4108814A公开(公告)日: 1978-08-22
- 发明人: Helmut Reiff , Wolfgang Wenzel , Jurgen Grammel , Dieter Dieterich
- 申请人: Helmut Reiff , Wolfgang Wenzel , Jurgen Grammel , Dieter Dieterich
- 申请人地址: DEX Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DEX Leverkusen
- 优先权: DEX2446440 19740928
- 主分类号: C08G18/08
- IPC分类号: C08G18/08 ; C08G18/38 ; C08G18/50 ; C08G18/12 ; C08G18/84
摘要:
This invention relates to a process for the production of water dispersible polyurethanes by reacting polyisocyanates with sulphonate group containing diols. The sulphonate diols have the general formula: ##STR1## WHEREIN A and B, which may be the same or different, each represents a divalent aliphatic hydrocarbon group containing from 1 to 6 carbon atoms,R represents hydrogen, an aliphatic hydrocarbon group containing 1 to 4 carbon atoms or a phenyl group,X.sup.(+) represents an alkali metal cation or ammonium group which may be substitutedn and m, which may be the same or different, each represents an integer between 0 and 30 inclusive,o and p, represent 0 or 1, andq represents an integer of 0 or 2.Sufficient amounts of this diol are used to provide the final polymer with a sulphonate group content of about 0.1 to 6 wt.%. In a preferred embodiment, a prepolymer is formed in substance with the sulphonate bearing diol, the polyisocyanate and optionally other reactive hydrogen bearing compounds. The prepolymer is then chain extended with water and water soluble polyamines. This second stage may take place in water and the polyamines may carry sulphonate groups.
公开/授权文献
- US5787045A Internal address generator of semiconductor memory device 公开/授权日:1998-07-28
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