发明授权
- 专利标题： Hydrogenation of aromatic nitriles to primary amines
- 专利标题（中）： 将芳族腈氢化成伯胺
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申请号： US8310申请日： 1979-02-01
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公开(公告)号： US4186146A公开(公告)日： 1980-01-29
- 发明人: Walter A. Butte, Jr. , William J. Murtaugh
- 申请人： Walter A. Butte, Jr. , William J. Murtaugh
- 申请人地址： PA Philadelphia
- 专利权人： Suntech, Inc.
- 当前专利权人： Suntech, Inc.
- 当前专利权人地址： PA Philadelphia
- 主分类号： C07B61/00
- IPC分类号： C07B61/00 ; B01J23/00 ; C07C67/00 ; C07C209/00 ; C07C209/48 ; C07C211/27 ; C07C85/12
摘要：
In the process of hydrogenating aromatic nitriles to primary amines whereby the nitrile is hydrogenated in a solvent system containing added ammonia using a cobalt or nickel catalyst, the improvement of employing an ether as solvent and carrying out the hydrogenation in the presence of water in an amount of from about 10% to about 20% by volume of the ether solvent whereby the rate of reaction is increased, secondary amine by-products are reduced and catalyst may be recycled without adverse effects.
公开/授权文献
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