Catalyst for hydrogenation of aromatic dinitriles
    2.
    发明授权
    Catalyst for hydrogenation of aromatic dinitriles 失效
    芳族二腈的氢化催化剂

    公开(公告)号:US4320032A

    公开(公告)日:1982-03-16

    申请号:US184588

    申请日:1980-09-05

    CPC分类号: B01J23/8913 C07C209/48

    摘要: In the process of hydrogenating an aromatic dinitrile to the corresponding di-primary amine in the presence of a catalyst, the improvement of using as catalyst a cobalt catalyst promoted with rhodium where the weight ratio of rhodium to cobalt is 1.0 or less.

    摘要翻译: 在催化剂存在下将芳族二腈氢化成相应的二伯胺的过程中,以铑与钴的重量比为1.0以下的铑催化剂的催化剂的改进。

    Carbon slurry fuels
    3.
    发明授权
    Carbon slurry fuels 失效
    碳浆燃料

    公开(公告)号:US4306882A

    公开(公告)日:1981-12-22

    申请号:US237225

    申请日:1981-02-23

    IPC分类号: C10L1/32

    CPC分类号: C10L1/32

    摘要: A liquid composition suitable as a high performance fuel and having improved rheological and stability properties comprising a liquid hydrocarbon having carbon particles dispersed therein of at least two disparate particle sizes, one of said carbon particles having an average particle diameter of from about 300 to about 350 mu and the other particle having an average particle diameter of about 60 to about 80 mu.

    摘要翻译: 一种适合作为高性能燃料并具有改进的流变学和稳定性质的液体组合物,其包含其中分散有至少两种不同粒径的碳颗粒的液态烃,所述碳颗粒之一的平均粒径为约300至约350 mu,另一个颗粒的平均粒径为约60至约80μm。

    Selecting perfluorocarbon compounds for synthetic blood
    4.
    发明授权
    Selecting perfluorocarbon compounds for synthetic blood 失效
    选择合成血液的全氟化碳化合物

    公开(公告)号:US4289499A

    公开(公告)日:1981-09-15

    申请号:US189509

    申请日:1980-09-22

    IPC分类号: A61K9/00 A61K31/02

    摘要: A process for selecting a perfluorocarbon compound from those having about 9 to 12 carbon atoms for preparing synthetic blood compositions. The process involves determining the critical solution temperature of the perfluorocarbon compound in a solvent such as n-hexane. The perfluorocarbon compound is accepted as suitable for preparing a synthetic blood composition if its critical solution temperature falls below a selected temperature set by the number of carbon atoms in the perfluorocarbon compound.

    摘要翻译: 从具有约9至12个碳原子的那些中选择全氟化碳化合物以制备合成血液组合物的方法。 该方法包括确定全氟化碳化合物在溶剂如正己烷中的临界溶解温度。 如果全氟化碳化合物的临界溶解温度低于由全氟化碳化合物中的碳原子数设定的选定温度,则该全氟化碳化合物被认为适于制备合成血液组合物。

    Separation of ammonia from ammonia containing gases
    5.
    发明授权
    Separation of ammonia from ammonia containing gases 失效
    从含氨气体中分离氨

    公开(公告)号:US4287162A

    公开(公告)日:1981-09-01

    申请号:US58695

    申请日:1979-07-18

    CPC分类号: C01C1/12 B01D53/14

    摘要: A process for the separation and recovery of substantially pure ammonia from its admixture with gases, particularly with gases containing carbon dioxide and gases obtained from the catalytic ammoxidation of hydrocarbons to the corresponding nitriles, by scrubbing the ammonia containing gases with an aqueous solution containing a mixture of salts having different cations and the anions of one or more inorganic acids capable of absorbing and liberating ammonia; e.g., mixtures of different alkali metal salts of phosphoric, telluric, boric, vanadic, chromic, selenic, germanic, silicic and similar acids. Preferably the anion component will be at least one of phosphoric, chromic, or boric acids.

    摘要翻译: 一种从与其气体混合物中分离和回收基本上纯氨的方法,特别是将含有二氧化碳和气体的气体从通过烃催化氨氧化成相应的腈得到的气体,通过用含有混合物的水溶液洗涤含氨气体 的具有不同阳离子的盐和能够吸收和释放氨的一种或多种无机酸的阴离子; 例如磷酸,碲,硼,钒,铬,硒,锗,硅和类似酸的不同碱金属盐的混合物。 优选地,阴离子组分将是磷酸,铬酸或硼酸中的至少一种。

    Cyanoalkylation process
    7.
    发明授权
    Cyanoalkylation process 失效
    氰基烷基化方法

    公开(公告)号:US4271089A

    公开(公告)日:1981-06-02

    申请号:US54771

    申请日:1979-07-05

    IPC分类号: C07C120/00

    摘要: In a cyanoalkylation process involving the reaction of a cyanoalkene compound such as acrylonitrile with a compound containing a labile hydrogen such as ethylene glycol, to form a cyanoalkylated product such as 3,3'-ethylenedioxy-bis(propionitrile), the reaction is carried out in the presence of cyanoalkylated product in addition to the cyanoalkylated product which is formed in situ by reaction of the reactants. High yields of cyanoalkylated product and low formation of by-products are obtained.

    摘要翻译: 在涉及氰基烯烃化合物例如丙烯腈与含有不稳定氢的化合物如乙二醇反应的氰基烷基化方法中,形成诸如3,3'-亚乙二氧基 - 双(丙腈)的氰基烷基化产物,进行反应 在氰基烷基化产物存在的情况下,除了通过反应物的反应原位形成的氰基烷基化产物之外。 获得高产率的氰基烷基化产物和低副产物形成。

    Decolorization of norbornadiene dimers
    10.
    发明授权
    Decolorization of norbornadiene dimers 失效
    降冰片二烯二聚体脱色

    公开(公告)号:US4229612A

    公开(公告)日:1980-10-21

    申请号:US7112

    申请日:1979-01-29

    CPC分类号: C07C13/64 C07C5/29 C07C7/12

    摘要: The removal of color bodies from an olefinic or saturated endo-endo hexacyclic homodimer of norbornadiene or mixtures thereof is accomplished by the use of a serpentine clay. Also acid bentonite clay or a montmorillonite clay can be used to remove the color bodies from the saturated dimer. The saturated dimer has a high density and a high heat of combustion making it useful as a missile fuel. Removal of the color bodies avoids possible catalyst poisoning in the hydrogenation of the olefinic to the saturated dimer. Also removal of the color bodies from the saturated dimer eliminates the possible problem of a material precipitating out on engine turbine blades and causing maintenance or operational problems.

    摘要翻译: 通过使用蛇纹石粘土来实现从降冰片二烯的烯属或饱和内六角六环同系二聚体或其混合物中去除着色体。 酸性膨润土或蒙脱石粘土也可用于从饱和二聚体中除去颜色体。 饱和二聚体具有高密度和高的燃烧热,使其可用作导弹燃料。 去除颜色体可以避免在烯烃氢化成饱和二聚体时催化剂中毒。 从饱和二聚体中去除颜色体也消除了在发动机涡轮叶片上析出物质并导致维护或操作问题的可能问题。