摘要:
In the process of hydrogenating an aromatic dinitrile to the corresponding di-primary amine in the presence of a catalyst, the improvement of using as catalyst a cobalt catalyst promoted with rhodium where the weight ratio of rhodium to cobalt is 1.0 or less.
摘要:
A liquid composition suitable as a high performance fuel and having improved rheological and stability properties comprising a liquid hydrocarbon having carbon particles dispersed therein of at least two disparate particle sizes, one of said carbon particles having an average particle diameter of from about 300 to about 350 mu and the other particle having an average particle diameter of about 60 to about 80 mu.
摘要:
A process for selecting a perfluorocarbon compound from those having about 9 to 12 carbon atoms for preparing synthetic blood compositions. The process involves determining the critical solution temperature of the perfluorocarbon compound in a solvent such as n-hexane. The perfluorocarbon compound is accepted as suitable for preparing a synthetic blood composition if its critical solution temperature falls below a selected temperature set by the number of carbon atoms in the perfluorocarbon compound.
摘要:
A process for the separation and recovery of substantially pure ammonia from its admixture with gases, particularly with gases containing carbon dioxide and gases obtained from the catalytic ammoxidation of hydrocarbons to the corresponding nitriles, by scrubbing the ammonia containing gases with an aqueous solution containing a mixture of salts having different cations and the anions of one or more inorganic acids capable of absorbing and liberating ammonia; e.g., mixtures of different alkali metal salts of phosphoric, telluric, boric, vanadic, chromic, selenic, germanic, silicic and similar acids. Preferably the anion component will be at least one of phosphoric, chromic, or boric acids.
摘要:
Hydrogenolysis of a saturated endo-endo dihydronorbornadiene hexacyclic dimer involves the use of a catalytic amount of a Group VIII metal and the presence of hydrogen. The resulting pentacyclic isomers can be used as a diluent for depressing the freezing point of the saturated hexacyclic dimer which is a component of a high density missile fuel.
摘要:
In a cyanoalkylation process involving the reaction of a cyanoalkene compound such as acrylonitrile with a compound containing a labile hydrogen such as ethylene glycol, to form a cyanoalkylated product such as 3,3'-ethylenedioxy-bis(propionitrile), the reaction is carried out in the presence of cyanoalkylated product in addition to the cyanoalkylated product which is formed in situ by reaction of the reactants. High yields of cyanoalkylated product and low formation of by-products are obtained.
摘要:
In the process of hydrogenating an aromatic dinitrile to the corresponding di-primary amine in the presence of a catalyst, the improvement of using as catalyst a cobalt catalyst promoted with rhodium where the weight ratio of rhodium to cobalt is 1.0 or less.
摘要:
The oxidation of methyl benzenes, such as toluene, with air or oxygen in the presence of acetic anhydride and sulfuric acid catalyst to form a phenolic acetate and methylene diacetate may be carried out under mild conditions when small amounts of benzaldehyde are added to the reaction.The resulting acetates may then be pyrolyzed to yield phenolic compounds and formaldehyde, respectively.
摘要:
The removal of color bodies from an olefinic or saturated endo-endo hexacyclic homodimer of norbornadiene or mixtures thereof is accomplished by the use of a serpentine clay. Also acid bentonite clay or a montmorillonite clay can be used to remove the color bodies from the saturated dimer. The saturated dimer has a high density and a high heat of combustion making it useful as a missile fuel. Removal of the color bodies avoids possible catalyst poisoning in the hydrogenation of the olefinic to the saturated dimer. Also removal of the color bodies from the saturated dimer eliminates the possible problem of a material precipitating out on engine turbine blades and causing maintenance or operational problems.