发明授权
- 专利标题: Catalytic conversion of aromatic fractions in the presence of steam
- 专利标题(中): 在蒸气存在下催化转化芳烃馏分
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申请号: US52359申请日: 1979-06-27
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公开(公告)号: US4268702A公开(公告)日: 1981-05-19
- 发明人: Daniel Duprez , Michel Grand
- 申请人: Daniel Duprez , Michel Grand
- 申请人地址: FRX Paris
- 专利权人: Elf France
- 当前专利权人: Elf France
- 当前专利权人地址: FRX Paris
- 优先权: FRX7820265 19780707
- 主分类号: C10G35/085
- IPC分类号: C10G35/085 ; C10G35/095
摘要:
A process for the catalytic conversion of aromatic fractions additionally containing variable proportions of C.sub.5 to C.sub.11 non-aromatic hydrocarbons, to obtain substantially pure benzene and hydrogen, by water dealkylation of the aromatic hydrocarbons and simultaneous reforming of the non-aromatic hydrocarbons, characterized in that aromatic fractions having boiling points which may be varied depending on the yield of hydrogen desired, are treated by steam at temperatures from 350.degree. C. to 600.degree. C., at a pressure of 1 to 80 bars, a volume of liquid passed per unit volume of catalyst of 0.1 to 10 and a water/hydrocarbon charge flow rate ratio of 0.2 to 4, in the presence of a dealkylation catalyst selected from at least one group VIII metal, on a support selected from a sieve L, a pretreated gamma alumina, and a mixed spinel (M.sub.x M'.sub.1-x) Al.sub.2 O.sub.4, M being a non-noble group VIII metal, and M' being selected from the group consisting of magnesium, manganese, and copper.
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