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    Water dealkylation catalyst of aromatic hydrocarbons
    1.
    发明授权
    Water dealkylation catalyst of aromatic hydrocarbons 失效
    芳烃的水脱烷基催化剂

    公开(公告)号：US4238368A

    公开(公告)日：1980-12-09

    申请号：US970332

    申请日：1978-12-18

    申请人： Daniel Duprez ,  Michel Grand

    发明人： Daniel Duprez ,  Michel Grand

    IPC分类号： B01J29/58 ,  B01J29/60 ,  B01J29/61 ,  B01J29/62 ,  B01J29/64 ,  B01J29/72 ,  C07B61/00 ,  C07C1/00 ,  C07C4/20 ,  C07C15/00 ,  C07C15/02 ,  C07C15/04 ,  C07C67/00 ,  B01J29/04 ,  B01J29/28

    CPC分类号： B01J29/61 ,  B01J29/60 ,  B01J29/64 ,  C07C4/20 ,  B01J2229/36 ,  C07C2529/61

    摘要： Catalyst for water dealkylation of oil fractions containing monoalkylated or polyalkylated aromatic hydrocarbons, said catalyst containing at least one metal of group VIII in a proportion of 0.1 to 5% by weight on a carrier, characterized in that said carrier is a zeolite L that can be exchanged with either alkaline cations or polyvalent cations of groups V.sub.b, VI.sub.b and VII.sub.b. The zeolite L can be exchanged with a solution of metals such as lithium, sodium, caesium, chromium, manganese, and rhodium. A method of using the catalyst by contacting the hydrocarbons with the catalyst at a temperature of 400.degree.-600.degree. C., a pressure of 0-80 bars, a space velocity of the hydrocarbon of from 0.1 to 10h.sup.-1, and a water to hydrocarbon mol ratio of 2-20.

    摘要翻译： 含有单烷基化或多烷基化芳烃的油馏分的水脱烷基化催化剂，所述催化剂在载体上含有0.1-5重量％的至少一种第VIII族金属，其特征在于所述载体是可以是 与碱性阳离子或Vb，VIb和VIIb族的多价阳离子交换。 沸石L可以与金属如锂，钠，铯，铬，锰和铑的溶液进行交换。 通过使烃与催化剂在400〜600℃的温度，0-80巴的压力，0.1〜10h -1的空间速度和水 与烃摩尔比为2-20。

    Catalytic conversion of aromatic fractions in the presence of steam
    2.
    发明授权
    Catalytic conversion of aromatic fractions in the presence of steam 失效
    在蒸气存在下催化转化芳烃馏分

    公开(公告)号：US4268702A

    公开(公告)日：1981-05-19

    申请号：US52359

    申请日：1979-06-27

    申请人： Daniel Duprez ,  Michel Grand

    发明人： Daniel Duprez ,  Michel Grand

    IPC分类号： C10G35/085 ,  C10G35/095

    CPC分类号： C10G35/095 ,  C10G35/085

    摘要： A process for the catalytic conversion of aromatic fractions additionally containing variable proportions of C.sub.5 to C.sub.11 non-aromatic hydrocarbons, to obtain substantially pure benzene and hydrogen, by water dealkylation of the aromatic hydrocarbons and simultaneous reforming of the non-aromatic hydrocarbons, characterized in that aromatic fractions having boiling points which may be varied depending on the yield of hydrogen desired, are treated by steam at temperatures from 350.degree. C. to 600.degree. C., at a pressure of 1 to 80 bars, a volume of liquid passed per unit volume of catalyst of 0.1 to 10 and a water/hydrocarbon charge flow rate ratio of 0.2 to 4, in the presence of a dealkylation catalyst selected from at least one group VIII metal, on a support selected from a sieve L, a pretreated gamma alumina, and a mixed spinel (M.sub.x M'.sub.1-x) Al.sub.2 O.sub.4, M being a non-noble group VIII metal, and M' being selected from the group consisting of magnesium, manganese, and copper.

    摘要翻译： 芳烃馏分催化转化另外含有可变比例的C 5至C 11非芳族烃的方法，通过芳族烃的水脱烷基化和非芳族烃的同时重整来获得基本上纯的苯和氢，其特征在于， 沸点可以根据所需氢气的产率而变化的芳族馏分在350℃至600℃的温度下以1至80巴的压力进行处理，每单位通过的液体体积 催化剂体积为0.1至10，水/烃充电流速比为0.2至4，在选自至少一种VIII族金属的脱烷基化催化剂存在下，在选自筛L，预处理的γ氧化铝 ，和混合尖晶石（MxM'1-x）Al2O4，M是非贵金属Ⅷ族金属，M'选自镁，锰和铜。

    Soil sampler
    5.
    发明授权
    Soil sampler 有权
    土壤采样器

    公开(公告)号：US09500567B2

    公开(公告)日：2016-11-22

    申请号：US14285865

    申请日：2014-05-23

    申请人： David Scheiderer ,  Michel Grand ,  Dwayne Maddux ,  Evan Delk

    发明人： David Scheiderer ,  Michel Grand ,  Dwayne Maddux ,  Evan Delk

    IPC分类号： G01N1/08 ,  G01N1/04 ,  G01N1/02

    CPC分类号： G01N1/08 ,  G01N1/04 ,  G01N2001/021 ,  G01N2001/085

    摘要： An automated soil sampler is removably mounted on an agricultural tractor and collects soil samples in a farm field while the tractor is driven through the field. At a periodic interval, the soil sampler momentarily lowers a soil collection knife into the soil to collect a soil sample, raises the collection knife out of the soil, and transfers the collected soil sample into a bar-coded storage container. The GPS location of the soil sample is associated with the storage container's bar-code in a data file. The interval between successive periodic soil samples corresponds to a determined forward displacement of the tractor. Storage containers that have received soil samples are moved to a storage area until all of the soil samples for a given field have been collected.

    摘要翻译： 自动土壤取样器可拆卸地安装在农用拖拉机上，并在拖拉机被驱赶通过田地时在农田中收集土壤样品。 以周期性间隔，土壤采样器将土壤采集器立即降低到土壤中以收集土壤样品，将采集刀从土壤中提取，并将收集的土壤样品转移到条形储存容器中。 土壤样品的GPS位置与数据文件中的存储容器的条形码相关联。 连续周期性土壤样品之间的间隔对应于确定的拖拉机向前位移。 已经接收土壤样品的储存容器移动到存储区域，直到收集给定场地的所有土壤样品。

    Soil sampler and method
    6.
    发明授权
    Soil sampler and method 有权
    土壤采样器和方法

    公开(公告)号：US09116078B1

    公开(公告)日：2015-08-25

    申请号：US13686014

    申请日：2012-11-27

    申请人： David Scheiderer ,  Michel Grand ,  Dwayne Maddox

    发明人： David Scheiderer ,  Michel Grand ,  Dwayne Maddox

    IPC分类号： G01N1/04

    CPC分类号： G01N1/04 ,  A01B79/02 ,  A01C21/007 ,  G01N1/08 ,  G01N2001/021

    摘要： An automatic soil sampler for taking samples of topsoil has a soil breakdown assembly that cuts a shallow furrow in the soil and moves debris to the side. Soil is collected with a sampling knife having a series of empty chambers adapted to receive samples of topsoil. A rotating discus is disposed opposite the soil sampling empty chambers for urging soil into the soil sampling empty chambers. A cup carrousel carries empty identified cups for receiving soil samples. A delivery assembly places one of the empty identified cup in a cup receiving station. A filling assembly connects the knife chambers carrying collected soil samples with the cup receiving station. The cups are filled with soil samples in a collecting station. Each filled cup has its identifier sent to memory along with the location at which the sample was taken.

    摘要翻译： 用于采集表层土样的自动土壤取样器具有土壤分解组件，其在土壤中切割浅沟，并将碎屑移动到侧面。 用采样刀收集土壤，其具有适于接收表土的样品的一系列空室。 旋转的铁饼放置在与土壤取样空腔相对的位置，用于将土壤推入土壤采样空腔。 一个杯子转盘携带空的识别杯子接收土壤样品。 送货组件将空的识别杯子中的一个放入杯子接收台。 填充组件将携带收集的土壤样品的刀室连接到杯子接收站。 杯子里收集了土壤样品。 每个填充的杯子的标识符与采样的位置一起发送到存储器。

    SOIL SAMPLER
    7.
    发明申请
    SOIL SAMPLER 有权
    土壤采样器

    公开(公告)号：US20140251032A1

    公开(公告)日：2014-09-11

    申请号：US14285865

    申请日：2014-05-23

    申请人： David Scheiderer ,  Michel Grand ,  Dwayne Maddux ,  Evan Delk

    发明人： David Scheiderer ,  Michel Grand ,  Dwayne Maddux ,  Evan Delk

    IPC分类号： G01N1/08

    CPC分类号： G01N1/08 ,  G01N1/04 ,  G01N2001/021 ,  G01N2001/085

    摘要： An automated soil sampler is removably mounted on an agricultural tractor and collects soil samples in a farm field while the tractor is driven through the field. At a periodic interval, the soil sampler momentarily lowers a soil collection knife into the soil to collect a soil sample, raises the collection knife out of the soil, and transfers the collected soil sample into a bar-coded storage container. The GPS location of the soil sample is associated with the storage container's bar-code in a data file. The interval between successive periodic soil samples corresponds to a determined forward displacement of the tractor. Storage containers that have received soil samples are moved to a storage area until all of the soil samples for a given field have been collected.

    摘要翻译： 自动土壤取样器可拆卸地安装在农用拖拉机上，并在拖拉机被驱赶通过田地时在农田中收集土壤样品。 以周期性间隔，土壤采样器将土壤采集器立即降低到土壤中以收集土壤样品，将采集刀从土壤中提取，并将收集的土壤样品转移到条形储存容器中。 土壤样品的GPS位置与数据文件中的存储容器的条形码相关联。 连续周期性土壤样品之间的间隔对应于确定的拖拉机向前位移。 已经接收土壤样品的储存容器移动到存储区域，直到收集给定场地的所有土壤样品。