发明授权
US4384132A Bis-(silylethyl)-oligosulphides and process for their production
失效
双(甲硅烷基乙基) - 二硫化物及其生产方法
- 专利标题: Bis-(silylethyl)-oligosulphides and process for their production
- 专利标题(中): 双(甲硅烷基乙基) - 二硫化物及其生产方法
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申请号: US282949申请日: 1981-07-13
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公开(公告)号: US4384132A公开(公告)日: 1983-05-17
- 发明人: Rudolf Schwarz , Peter Kleinschmit , Christa Liedtke , Siegfried Wolff
- 申请人: Rudolf Schwarz , Peter Kleinschmit , Christa Liedtke , Siegfried Wolff
- 申请人地址: DEX Frankfurt
- 专利权人: Degussa Aktiengesellschaft
- 当前专利权人: Degussa Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt
- 优先权: DEX2856229 19781227
- 主分类号: C08L7/00
- IPC分类号: C08L7/00 ; C07F7/08 ; C07F7/12 ; C07F7/18 ; C08G75/02 ; C08G75/14 ; C08K5/5425 ; C08K5/548 ; C08L21/00 ; C08L23/00 ; C08L33/00 ; C08L33/02 ; C08L101/00
摘要:
Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m -- SiR.sub.n.sup.1 R.sub.4 -(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 -C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 -C.sub.3 -alkyl, phenyl or C.sub.5 -C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.
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