Bis-(silylethyl)-oligosulphides and process for their production
    1.
    发明授权
    Bis-(silylethyl)-oligosulphides and process for their production 失效
    双(甲硅烷基乙基) - 二硫化物及其生产方法

    公开(公告)号:US4444936A

    公开(公告)日:1984-04-24

    申请号:US461432

    申请日:1983-01-27

    摘要: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m --SiR.sub.n.sup.1 R.sub.4--(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 --C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 --C.sub.3 -alkyl, phenyl or C.sub.5 --C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

    摘要翻译: 通过使式(CH2 = CH)m-SiRn1R4-(m + n)的乙烯基硅烷(其中R表示氯,溴,碘,C1-C3-烷氧基,2-甲基苯基) 甲氧基乙氧基,2-乙氧基乙氧基或羟基,R1代表C1-C3-烷基,苯基或C5-C7-环烷基,n是0,1或2,m是1或2,m + n是1,2或3, 以及在给定情况下,在约100至200℃的温度下,乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴(反应总压力)温度的压力下,在本身已知的硫化催化剂的存在下,在给定的情况下,随后水解或部分水解反应产物。 双(甲硅烷基乙基) - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂(粘合剂),在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。

    Bis-(silylethyl)-oligosulphides and process for their production
    2.
    发明授权
    Bis-(silylethyl)-oligosulphides and process for their production 失效
    双(甲硅烷基乙基) - 二硫化物及其生产方法

    公开(公告)号:US4408064A

    公开(公告)日:1983-10-04

    申请号:US106862

    申请日:1979-12-26

    摘要: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m -SiR.sub.n.sup.1 R.sub.4-(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 -C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 -C.sub.3 -alkyl, phenyl or C.sub.5 -C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

    摘要翻译: 通过使式(CH2 = CH)m-SiRn1R4-(m + n)的乙烯基硅烷(其中R表示氯,溴,碘,C1-C3-烷氧基,2-甲基苯基) 甲氧基乙氧基,2-乙氧基乙氧基或羟基,R1代表C1-C3-烷基,苯基或C5-C7-环烷基,n是0,1或2,m是1或2,m + n是1,2或3, 以及在给定情况下,在约100至200℃的温度下,乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴的压力(在反应温度下的总压力)和本身已知的硫化催化剂的存在下,在给定的情况下随后水解或部分水解反应产物。 双(甲硅烷基乙基) - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂(粘合剂),在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。

    Bis-(silylethyl)-oligosulphides and process for their production
    3.
    发明授权
    Bis-(silylethyl)-oligosulphides and process for their production 失效
    双(甲硅烷基乙基) - 二硫化物及其生产方法

    公开(公告)号:US4384132A

    公开(公告)日:1983-05-17

    申请号:US282949

    申请日:1981-07-13

    摘要: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m -- SiR.sub.n.sup.1 R.sub.4 -(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 -C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 -C.sub.3 -alkyl, phenyl or C.sub.5 -C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

    摘要翻译: 通过使式(CH2 = CH)m -SiRn1R4 - (m + n)的乙烯基硅烷(其中R表示氯,溴,碘,C1-C3-烷氧基,2-甲基苯基) 甲氧基乙氧基,2-乙氧基乙氧基或羟基,R1代表C1-C3-烷基,苯基或C5-C7-环烷基,n是0,1或2,m是1或2,m + n是1,2或3, 以及在给定情况下,在约100至200℃的温度下,乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴的压力(在反应温度下的总压力)和本身已知的硫化催化剂的存在下,在给定的情况下随后水解或部分水解反应产物。 双(甲硅烷基乙基) - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂(粘合剂),在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。

    Hair cutter
    4.
    发明授权
    Hair cutter 失效
    理发师

    公开(公告)号:US4011656A

    公开(公告)日:1977-03-15

    申请号:US588986

    申请日:1975-06-20

    申请人: Christa Liedtke

    发明人: Christa Liedtke

    IPC分类号: B26B21/00 B26B21/40 B26B21/12

    摘要: A hair cutter comprising a cover plate displaceably disposed relative to and opposite a blade carrier plate, the cover plate having a row of teeth covering a blade cutting edge. Downwardly pointing teeth-like arresting projections are mounted on a flanged downwardly facing part of the blade carrier plate and positively engage upwardly pointing arresting teeth on lateral shoulders of a push button actuating element, the latter disposed perpendicular to the plane of the blade. The arresting projections are biased into an arresting position and are releasable by a push button actuating element which slidably projects through a complementary opening formed in the cover plate, whereby the arresting teeth of the shoulders being released from the downwardly pointing and complementary arresting teeth upon pushing the push button actuating element downwardly.

    摘要翻译: 一种切割器,包括可相对于叶片承载板可移动地布置的盖板,所述盖板具有覆盖叶片切割边缘的一排齿。 向下指向齿状的止动突起安装在叶片承载板的凸缘向下的部分上,并且与按钮致动元件的侧肩上的向上指向的止动齿积极地接合,后者设置成垂直于叶片的平面。 止动突起被偏压到止动位置,并且可通过按钮致动元件释放,按钮致动元件可滑动地突出穿过形成在盖板中的互补开口,由此肩部的止动齿从推动时向下指向和互补的止动齿释放 按钮致动元件向下。

    Haircutter
    5.
    发明授权
    Haircutter 失效
    理发师

    公开(公告)号:US3986258A

    公开(公告)日:1976-10-19

    申请号:US466119

    申请日:1974-05-02

    申请人: Christa Liedtke

    发明人: Christa Liedtke

    IPC分类号: B26B21/08 B26B21/16 B26B21/42

    CPC分类号: B26B21/08

    摘要: A hair cutter comprising a blade interchangeably retained between a blade-supporting plate and a cover plate, the latter having a row of teeth which overlaps said blade cutting edge. The plates are displaceable perpendicularly to the blade cutting edge and relatively to one another between two end positions, and the blade-supporting plate bears the blade as far as adjacent the cutting edge, yet leaving the blade cutting edge exposed. In a zone adjoining the blade cutting edge, the blade-supporting plate has at least in part a wedge-shaped portion increasing in thickness extending from the blade cutting edge in a rearward direction, so that when the hair cutter is placed on the head of the user the blade is adjustable to a cutting angle determined by front ends of the teeth and application portions of the wedge-shaped portion on the user's head. A coupling member is disposed on each of the two plates for locating the plates with respect to one another in selectable displacement positions and a spring retains the coupling members with prestressing in positive engagement with one another, an actuating element extending through one of the two plates and being accessible from an outside, and movably retained perpendicularly to the plane of the blade, and engaging with one of the coupling members and disengaging the latter on actuation against the spring.

    摘要翻译: 一种剪刀,包括可互换地保持在叶片支撑板和盖板之间的刀片,刀片具有与所述刀片切割刃重叠的一排齿。 板可以在两个端部位置之间垂直于叶片切割刃相对移动,并且叶片支撑板将刀片承载在与切割边缘相邻的位置,同时使叶片切割刃露出。 在与刀刃切割边缘相邻的区域中,刀片支撑板至少部分地具有从刀片切割刃向后延伸的厚度增加的楔形部分,使得当将剪发器放置在 使用者刀片可调节到由使用者头部的楔形部分的齿的前端和施加部分确定的切割角度。 联接构件设置在两个板中的每一个上,用于在可选择的位移位置中相对于彼此定位板,并且弹簧将联接构件保持为彼此正向接合的预应力,致动元件延伸穿过两个板之一 并且可从外部接近并且可移动地保持垂直于叶片的平面,并且与联接构件中的一个接合,并且在致动时使弹簧与弹簧分离。