发明授权
- 专利标题: Pre-expanded plastic beads based on poly-para-methylstyrene
- 专利标题(中): 基于聚对甲基苯乙烯的预膨胀塑料珠
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申请号: US531823申请日: 1983-09-13
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公开(公告)号: US4459373A公开(公告)日: 1984-07-10
- 发明人: Klaus Hahn , Isidoor De Grave , Rupert Schick
- 申请人: Klaus Hahn , Isidoor De Grave , Rupert Schick
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX3234664 19820918
- 主分类号: C08F2/18
- IPC分类号: C08F2/18 ; C08F2/38 ; C08F2/44 ; C08F12/12 ; C08J9/20 ; C08J9/18
摘要:
The invention relates to pre-expanded plastic beads based on poly-para-methylstyrene with the following properties:(a) the bead size lies between 0.2 and 3 cm,(b) the thermal stability, measured in accordance with DIN 53,424 is above 110.degree. C., and(c) the bulk density is below 35 g/l.The corresponding expandable plastic beads are prepared through the polymerization of para-methylstyrene in an aqueous suspension with the addition of volatile organic blowing agents during or after polymerization, whereby polymerization occurs in the presence of molecular-weight-regulating substances. Typical molecular-weight-regulating substances are organic chain transfer agents with a transfer constant K between 0.1 and 50, said agents being added in amounts ranging from 0.1 percent by weight to 1 percent by weight when a yield ranging from 20 to 95 percent is reached. Oligomers of the styrene or para-methylstyrene in quantities from 0.1 percent by weight to 10 percent by weight may also be employed.
公开/授权文献
- US5562928A Injection molding apparatus for molding an indicating member 公开/授权日:1996-10-08
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