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US4467081A Gelable, silicate rich resins from hydrophobic polyols and volatile and/or incompatible organosilicates 失效
来自疏水多元醇和挥发性和/或不相容的有机硅酸盐的可凝胶的,富含硅酸盐的树脂

Gelable, silicate rich resins from hydrophobic polyols and volatile
and/or incompatible organosilicates
Abstract:
Disclosed is a resin comprising a reaction product prepared by partially reacting to homogeneity a hydrophobic polyol and an organosilicon-containing material comprising an organosilicon-containing substance. The organosilicon-containing substance has atoms bonded directly to silicon, all of which atoms are selected from oxygen, nitrogen, and/or chlorine, and additionally has moieties directly bonded to silicon which are easily displaceable by reaction with water and/or alcohol. At least a part of the organosilicon-containing substance is hydrolyzed. The reaction product is homogeneous and contains residual hydroxyl moieties from the hydrophobic polyol and residual moieties bonded directly to silicon which are easily displaceable. the reaction product is capable of self-curing, optionally with a catalyst, by reaction with moisture and/or with the residual hydroxyl moieties, of the residual moieties directly bonded to silicon which are easily displaceable.
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