发明授权
US4479005A Selective preparation of isomers and enantiomers of cyclopropane
carboxylic acids
失效
选择性制备环丙烷羧酸的异构体和对映异构体
- 专利标题: Selective preparation of isomers and enantiomers of cyclopropane carboxylic acids
- 专利标题(中): 选择性制备环丙烷羧酸的异构体和对映异构体
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申请号: US450500申请日: 1982-12-16
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公开(公告)号: US4479005A公开(公告)日: 1984-10-23
- 发明人: William A. Kleschick
- 申请人: William A. Kleschick
- 申请人地址: MI Midland
- 专利权人: The Dow Chemical Company
- 当前专利权人: The Dow Chemical Company
- 当前专利权人地址: MI Midland
- 主分类号: C07D263/26
- IPC分类号: C07D263/26 ; C07C69/74
摘要:
A process has been discovered for selective preparation of isomers and enantiomers of 2,2-dimethyl-3-(2,2-dihalovinyl)cyclopropane carboxylic acids. In this process an adduct of an alkyl 3,3-dimethyl-4-pentenoate and a substituted 2-oxazolidone is reacted with a substituted dihalomethane compound. The resulting compound is cyclized, dehydrohalogenated and hydrolyzed to yield the desired product. These cyclopropane carboxylic acids are useful precursors for pyrethroid insecticides.
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