发明授权
- 专利标题: Preparation of lithium initiator for the preparation of star polymers
- 专利标题(中): 制备星形聚合物的锂引发剂的制备
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申请号: US421699申请日: 1982-09-22
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公开(公告)号: US4497748A公开(公告)日: 1985-02-05
- 发明人: Francis J. Vitus , Ivan G. Hargis , Russell A. Livigni , Sundar L. Aggarwal
- 申请人: Francis J. Vitus , Ivan G. Hargis , Russell A. Livigni , Sundar L. Aggarwal
- 申请人地址: OH Akron
- 专利权人: The General Tire & Rubber Company
- 当前专利权人: The General Tire & Rubber Company
- 当前专利权人地址: OH Akron
- 主分类号: C08F236/10
- IPC分类号: C08F236/10 ; C08F297/04 ; C08L21/00 ; C08L67/06 ; C07F1/02
摘要:
Divinyl benzene and/or diisopropenyl benzene in hydrocarbon solvent is added over a period of time at low temperature to a hydrocarbon solvent containing a C.sub.2-20 normal, secondary or tertiary alkyl or cycloalkyl lithium compound and a tertiary alkylamine having 2-4 carbon atoms prepared at low temperature to provide an initiator having an average of from 4 to 9 C-Li sites and a VPO Mn of from about 750 to 4,000. These initiators are useful in polymerizing dienes and vinyl monomers to provide star polymers having an average of from about 4 to 9 arms or branches. These star polymers among other things are useful low profile or low shrink additives for FRPs, e.g., glass fiber reinforced plastics.
公开/授权文献
- USD328716S Bathroom scale 公开/授权日:1992-08-18
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