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    Preparation of star polymers
    1.
    发明授权
    Preparation of star polymers 失效
    星形聚合物的制备

    公开(公告)号：US4426495A

    公开(公告)日：1984-01-17

    申请号：US421700

    申请日：1982-09-22

    申请人： Francis J. Vitus ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    发明人： Francis J. Vitus ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    IPC分类号： C08F236/10 ,  C08F297/04 ,  C08L21/00 ,  C08L67/06

    CPC分类号： C08F236/10 ,  C08F297/042 ,  C08L21/00 ,  C08L67/06

    摘要： Divinyl benzene and/or diisopropenyl benzene in hydrocarbon solvent is added over a period of time at low temperature to a hydrocarbon solvent containing a C.sub.2-20 normal, secondary or tertiary alkyl or cycloalkyl lithium compound and a tertiary alkylamine having 2-4 carbon atoms prepared at low temperature to provide an initiator having an average of from 4 to 9 C-Li sites and a VPO Mn of from about 750 to 4,000. These initiators a re useful in polymerizing dienes and vinyl monomers to provide star polymers having an average of from about 4 to 9 arms or branches. These star polymers among other things are useful low profile or low shrink additives for FRPs, e.g., glass fiber reinforced plastics.

    摘要翻译： 将二乙烯基苯和/或二异丙烯基苯在烃溶剂中在一段时间内在低温下加入到含有C 2-20正，仲或叔烷基或环烷基锂化合物和具有2-4个碳原子的叔烷基胺的烃溶剂中 在低温下提供具有平均4至9个C-Li位点的引发剂和约750至4,000的VPO Mn。 这些引发剂可用于聚合二烯和乙烯基单体，以提供平均约4至9个臂或分支的星形聚合物。 这些星形聚合物在其它方面是用于FRP的低轮廓或低收缩添加剂，例如玻璃纤维增​​强塑料。

    Preparation of lithium initiator for the preparation of star polymers
    3.
    发明授权
    Preparation of lithium initiator for the preparation of star polymers 失效
    制备星形聚合物的锂引发剂的制备

    公开(公告)号：US4497748A

    公开(公告)日：1985-02-05

    申请号：US421699

    申请日：1982-09-22

    申请人： Francis J. Vitus ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    发明人： Francis J. Vitus ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    IPC分类号： C08F236/10 ,  C08F297/04 ,  C08L21/00 ,  C08L67/06 ,  C07F1/02

    CPC分类号： C08F236/10 ,  C08F297/042 ,  C08L21/00 ,  C08L67/06

    摘要： Divinyl benzene and/or diisopropenyl benzene in hydrocarbon solvent is added over a period of time at low temperature to a hydrocarbon solvent containing a C.sub.2-20 normal, secondary or tertiary alkyl or cycloalkyl lithium compound and a tertiary alkylamine having 2-4 carbon atoms prepared at low temperature to provide an initiator having an average of from 4 to 9 C-Li sites and a VPO Mn of from about 750 to 4,000. These initiators are useful in polymerizing dienes and vinyl monomers to provide star polymers having an average of from about 4 to 9 arms or branches. These star polymers among other things are useful low profile or low shrink additives for FRPs, e.g., glass fiber reinforced plastics.

    摘要翻译： 将二乙烯基苯和/或二异丙烯基苯在烃溶剂中在一段时间内在低温下加入到含有C 2-20正，仲或叔烷基或环烷基锂化合物和具有2-4个碳原子的叔烷基胺的烃溶剂中 在低温下提供具有平均4至9个C-Li位点和约750至4,000个VPO＆Upbar＆Mn的引发剂。 这些引发剂可用于聚合二烯和乙烯基单体以提供平均约4至9个臂或分枝的星形聚合物。 这些星形聚合物在其它方面是用于FRP的低轮廓或低收缩添加剂，例如玻璃纤维增​​强塑料。

    Tire tread having high trans butadiene based elastomeric block copolymers and blends
    6.
    发明授权
    Tire tread having high trans butadiene based elastomeric block copolymers and blends 失效
    轮胎胎面具有高反式丁二烯基弹性体嵌段共聚物和共混物

    公开(公告)号：US4669518A

    公开(公告)日：1987-06-02

    申请号：US848550

    申请日：1986-04-07

    申请人： Ivan G. Hargis ,  Hubert J. Fabris ,  Russell A. Livigni ,  Sundar L. Aggarwal ,  George B. Thomas ,  John A. Wilson

    发明人： Ivan G. Hargis ,  Hubert J. Fabris ,  Russell A. Livigni ,  Sundar L. Aggarwal ,  George B. Thomas ,  John A. Wilson

    IPC分类号： B60C1/00 ,  C08F297/04 ,  C08L53/02 ,  B60C11/00

    CPC分类号： C08F297/04 ,  B60C1/0016 ,  C08L53/02

    摘要： Rubbery high trans-high vinyl diblock copolymers, blends of rubbery high trans copolymers and rubbery high vinyl polymers, and mixtures (alloys or blends) of said diblock copolymers, high trans copolymers and high vinyl polymers are useful in producing tire treads exhibiting good processibility, good rolling resistance, skid resistance and abrasion resistance. The high trans block or copolymer comprises a copolymer of butadiene-1,3 and styrene and/or isoprene and the high vinyl block or polymer comprises polybutadiene or copolymers of butadiene and styrene and/or isoprene. These di-block copolymers, copolymers and polymers are made by solution polymerization. The diblock copolymer may be made by copolymerizing butadiene and styrene and/or isoprene using a Ba, Ca or Sr alcoholate, R.sub.2 Mg and R.sub.3 Al to from about 60 to 95% conversion to a high trans block and then adding (optionally more Bd with or without Sty and/or isoprene) a strong Lewis base and a Na, K or Rb alkoxide and continuing the polymerization to completion to obtain the high vinyl block of the di-block copolymer.

    摘要翻译： 橡胶状高反式高级乙烯基二嵌段共聚物，橡胶状高反式共聚物和橡胶状高级乙烯基聚合物的共混物以及所述二嵌段共聚物，高反式共聚物和高乙烯基聚合物的混合物（合金或共混物）可用于生产具有良好加工性能的轮胎胎面， 良好的滚动阻力，抗滑性和耐磨性。 高反式嵌段或共聚物包含丁二烯-1,3和苯乙烯和/或异戊二烯的共聚物，高乙烯基嵌段或聚合物包括聚丁二烯或丁二烯和苯乙烯和/或异戊二烯的共聚物。 这些二嵌段共聚物，共聚物和聚合物通过溶液聚合制备。 二嵌段共聚物可以通过使用Ba，Ca或Sr醇化物，R2Mg和R3Al使丁二烯和苯乙烯和/或异戊二烯共聚，从而将高转异构体转化为约60至95％，然后加入（任选地更多具有或不具有 Sty和/或异戊二烯）强路易斯碱和Na，K或Rb醇盐，并继续聚合至完成以获得二嵌段共聚物的高乙烯基嵌段。

    High trans butadiene based elastomeric block copolymers and blends
    7.
    发明授权
    High trans butadiene based elastomeric block copolymers and blends 失效
    高反式丁二烯基弹性体嵌段共聚物和共混物

    公开(公告)号：US4616065A

    公开(公告)日：1986-10-07

    申请号：US723385

    申请日：1985-04-15

    申请人： Ivan G. Hargis ,  Hubert J. Fabris ,  Russell A. Livigni ,  Sundar L. Aggarwal ,  George B. Thomas ,  John A. Wilson

    发明人： Ivan G. Hargis ,  Hubert J. Fabris ,  Russell A. Livigni ,  Sundar L. Aggarwal ,  George B. Thomas ,  John A. Wilson

    IPC分类号： C08F4/52 ,  B60C1/00 ,  C08F4/60 ,  C08F36/06 ,  C08F212/00 ,  C08F212/08 ,  C08F295/00 ,  C08F297/04 ,  C08K3/04 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C08L23/00 ,  C08L51/00 ,  C08L51/02 ,  C08L53/00 ,  C08L53/02 ,  C08L77/00 ,  C08L101/00 ,  C08L47/00

    CPC分类号： C08F297/04 ,  B60C1/0016 ,  C08L53/02 ,  Y10S152/905 ,  Y10T152/10495

    摘要： Rubbery high trans-high vinyl diblock copolymers, blends of rubbery high trans copolymers and rubbery high vinyl polymers, and mixtures (alloys or blends) of said diblock copolymers, high trans copolymers and high vinyl polymers are useful in producing tire treads exhibiting good processibility, good rolling resistance, skid resistance and abrasion resistance. The high trans block or copolymer comprises a copolymer of butadiene-1,3 and styrene and/or isoprene and the high vinyl block or polymer comprises polybutadiene or copolymers of butadiene and styrene and/or isoprene. These di-block copolymers, copolymers and polymers are made by solution polymerization. The diblock copolymer may be made by copolymerizing butadiene and styrene and/or isoprene using a Ba, Ca or Sr alcoholate, R.sub.2 Mg and R.sub.3 Al to from about 60 to 95% conversion to a high trans block and then adding (optionally more Bd with or without Sty and/or isoprene) a strong Lewis base and a Na, K or Rb alkoxide and continuing the polymerization to completion to obtain the high vinyl block of the di-block copolymer.

    摘要翻译： 橡胶状高反式高级乙烯基二嵌段共聚物，橡胶状高反式共聚物和橡胶状高级乙烯基聚合物的共混物以及所述二嵌段共聚物，高反式共聚物和高乙烯基聚合物的混合物（合金或共混物）可用于生产具有良好加工性能的轮胎胎面， 良好的滚动阻力，抗滑性和耐磨性。 高反式嵌段或共聚物包含丁二烯-1,3和苯乙烯和/或异戊二烯的共聚物，高乙烯基嵌段或聚合物包括聚丁二烯或丁二烯和苯乙烯和/或异戊二烯的共聚物。 这些二嵌段共聚物，共聚物和聚合物通过溶液聚合制备。 二嵌段共聚物可以通过使用Ba，Ca或Sr醇化物，R2Mg和R3Al使丁二烯和苯乙烯和/或异戊二烯共聚，从而将高转异构体转化为约60至95％，然后加入（任选地更多具有或不具有 Sty和/或异戊二烯）强路易斯碱和Na，K或Rb醇盐，并继续聚合至完成以获得二嵌段共聚物的高乙烯基嵌段。

    Solution polymerization
    8.
    发明授权
    Solution polymerization 失效
    溶液聚合

    公开(公告)号：US4297240A

    公开(公告)日：1981-10-27

    申请号：US178248

    申请日：1980-08-15

    申请人： Robert E. Bingham ,  Richard R. Durst ,  Hubert J. Fabris ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    发明人： Robert E. Bingham ,  Richard R. Durst ,  Hubert J. Fabris ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    IPC分类号： C08F4/50 ,  C08F4/54 ,  C08F36/04 ,  C08G65/12 ,  C08G65/14 ,  C08G77/08 ,  C08F4/10

    CPC分类号： C08G77/08 ,  C08F36/04 ,  C08F4/54 ,  C08G65/12 ,  C08G65/14

    摘要： A composition useful as a catalyst in solution polymerization comprises (1) a barium, calcium and/or strontium alcoholate, (2) an organoaluminum compound and (3) an organomagnesium compound. (2) and (3) may be used as a complex with (1). The compositions can be used to polymerize ethylenically unsaturated monomers like butadiene, butadiene and styrene, and isoprene and heterocyclic monomers like oxiranes, thiiranes, siloxanes, thiatanes and lactams. The catalyst composition can product polybutadienes and butadiene-styrene copolymers having a trans-1,4 content as high as 90%. The non-terminating features of the polymerization of this invention permit the preparation of functionally terminated butadiene based polymers and block polymers containing sufficient amounts of trans-1,4 butadiene units to crystallize.

    摘要翻译： 用作溶液聚合催化剂的组合物包括（1）钡，钙和/或锶醇盐，（2）有机铝化合物和（3）有机镁化合物。 （2）和（3）可以用作与（1）的络合物。 该组合物可用于聚合烯属不饱和单体如丁二烯，丁二烯和苯乙烯，异戊二烯和杂环单体如环氧乙烷，噻咯烷，硅氧烷，硫杂烷和内酰胺。 催化剂组合物可以产生具有高达90％的反式-1,4-含量的聚丁二烯和丁二烯 - 苯乙烯共聚物。 本发明聚合的非终止特征允许制备功能封端的基于丁二烯的聚合物和含有足够量的反式-1,4-丁二烯单元结晶的嵌段聚合物。

    Solution polymerization
    9.
    发明授权
    Solution polymerization 失效
    溶液聚合

    公开(公告)号：US4307218A

    公开(公告)日：1981-12-22

    申请号：US178272

    申请日：1980-08-15

    申请人： Robert E. Bingham ,  Richard R. Durst ,  Hubert J. Fabris ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    发明人： Robert E. Bingham ,  Richard R. Durst ,  Hubert J. Fabris ,  Ivan G. Hargis ,  Russell A. Livigni ,  Sundar L. Aggarwal

    IPC分类号： C08F4/54 ,  C08F36/04 ,  C08G65/12 ,  C08G65/14 ,  C08G77/08 ,  C08L9/06 ,  C08F236/00

    CPC分类号： C08F36/04 ,  C08F4/54 ,  C08G65/12 ,  C08G65/14 ,  C08G77/08 ,  C08K5/56 ,  C08L9/06

    摘要： A composition useful as a catalyst in solution polymerization comprises (1) a barium, calcium and/or strontium alcoholate, (2) an organoaluminum compound and (3) an organomagnesium compound. (2) and (3) may be used as a complex with (1). The compositions can be used to polymerize ethylenically unsaturated monomers like butadiene, butadiene and styrene, and isoprene and heterocyclic monomers like oxiranes, thiiranes, siloxanes, thiatanes and lactams. The catalyst composition can produce polybutadienes and butadiene-styrene copolymers having a trans-1,4 content as high as 90%. The non-terminating features of the polymerization of this invention permit the preparation of functionally terminated butadiene based polymers and block polymers containing sufficient amounts of trans-1,4 butadiene units to crystallize.

    摘要翻译： 用作溶液聚合催化剂的组合物包括（1）钡，钙和/或锶醇盐，（2）有机铝化合物和（3）有机镁化合物。 （2）和（3）可以用作与（1）的络合物。 该组合物可用于聚合烯属不饱和单体如丁二烯，丁二烯和苯乙烯，异戊二烯和杂环单体如环氧乙烷，噻咯烷，硅氧烷，硫杂烷和内酰胺。 催化剂组合物可以生产具有高达90％的反式-1,4-含量的聚丁二烯和丁二烯 - 苯乙烯共聚物。 本发明聚合的非终止特征允许制备功能封端的基于丁二烯的聚合物和含有足够量的反式-1,4-丁二烯单元结晶的嵌段聚合物。