发明授权
US4532269A Erodible terpolymer from tributyl tin acrylate or methacrylate and
paints for fouling control
失效
来自丙烯酸丁酯或甲基丙烯酸三丁基锡的可闻三元共聚物和污垢控制涂料
- 专利标题: Erodible terpolymer from tributyl tin acrylate or methacrylate and paints for fouling control
- 专利标题(中): 来自丙烯酸丁酯或甲基丙烯酸三丁基锡的可闻三元共聚物和污垢控制涂料
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申请号: US592635申请日: 1984-03-23
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公开(公告)号: US4532269A公开(公告)日: 1985-07-30
- 发明人: Melvin H. Gitlitz , David B. Russell , Howard H. Leiner
- 申请人: Melvin H. Gitlitz , David B. Russell , Howard H. Leiner
- 申请人地址: NJ Woodbridge
- 专利权人: M&T Chemicals Inc.
- 当前专利权人: M&T Chemicals Inc.
- 当前专利权人地址: NJ Woodbridge
- 主分类号: C08F220/00
- IPC分类号: C08F220/00 ; C08F30/00 ; C08F30/04 ; C08F220/10 ; C08K5/00 ; C09D5/08 ; C09D5/14 ; C09D5/16 ; C09D137/00 ; C08L33/08
摘要:
A novel polymeric binder for an antifouling paint includes greater than 2.5 to less than 25 mole percent of a unit from a tributyltin acrylate or methacrylate monomer group, an acrylic or methacrylic ester monomer unit having selected substituent groups in the ester moiety so that the ester is hydrolyzable at a suitable rate in seawater, and a copolymerizable ethylenically unsaturated monomer unit.The presence of the hydrolyzable ester group in the polymer binder of the present invention enables the paint to erode at a desired rate in seawater even with the low tin content in the polymer, thereby providing a desired low level of tin in solution and exposing a fresh paint surface periodically.
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