发明授权
- 专利标题: Ethylenically unsaturated N-(halosulfonyl) carbamyl monomers
- 专利标题(中): 乙烯基不饱和N-(卤代磺酰基)氨基甲酰基单体
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申请号: US674195申请日: 1984-11-23
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公开(公告)号: US4663475A公开(公告)日: 1987-05-05
- 发明人: Thomas E. Fisk
- 申请人: Thomas E. Fisk
- 申请人地址: MI Midland
- 专利权人: The Dow Chemical Company
- 当前专利权人: The Dow Chemical Company
- 当前专利权人地址: MI Midland
- 主分类号: C08F220/36
- IPC分类号: C08F220/36 ; C08F283/06 ; C07C125/03 ; C07C125/06 ; C07C125/065 ; C07C125/067
摘要:
A stable copolymer dispersion is prepared by addition copolymerization of (1) a monomeric adduct of an active hydrogen compound, e.g., a polyether polyol or polyether monool, and an ethylenically unsaturated N-chlorosulfonyl carbamyl compound such as acryloxyethylchlorosulfonylcarbamate or an unsaturated N-chlorocarbonyl carbamyl compound with (2) ethylenically unsaturated monomer(s), e.g., styrene or a mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound such as a polyether polyol. The molar ratio of carbamyl moiety to active hydrogen compound is preferably less than about 0.1:1. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
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