发明授权
- 专利标题: Process for producing benzophenone-azine
- 专利标题(中): 二苯甲酮吖嗪的制备方法
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申请号: US684419申请日: 1984-12-20
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公开(公告)号: US4751326A公开(公告)日: 1988-06-14
- 发明人: Takanari Nawata , Shuzabu Sakaguchi , Toshiaki Kohzaki , Osamu Aoki , Norio Takeda , Masafumi Shimpo
- 申请人: Takanari Nawata , Shuzabu Sakaguchi , Toshiaki Kohzaki , Osamu Aoki , Norio Takeda , Masafumi Shimpo
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX57-147151 19820825
- 主分类号: C07B61/00
- IPC分类号: C07B61/00 ; B01J27/00 ; B01J27/32 ; C07C67/00 ; C07C241/00 ; C07C251/88 ; C07C109/04
摘要:
An improved process for producing benzophenone-azine in which a catalyst can be removed, recovered and recycled is disclosed. The process comprises the steps of:(a) oxidizing benzophenone-imine with molecular oxygen in the presence of cuprous chloride catalyst to produce an oxidation reaction mixture containing benzophenone-azine;(b) contacting the oxidation reaction mixture obtained in step (a) with an aqueous solution containing ammonium chloride and hydrochloric acid to decompose the remaining benzophenone-imine substantially without causing decomposition of the produced benzophenone-azine and simultaneously to extract the catalyst from the oxidation reaction mixture;(c) separating the oxidation reaction mixture containing benzophenone-azine after the extraction in step (b) to recover benzophenone-azine as a solution;(d) neutralizing the catalyst-containing aqueous solution separated after the extraction step (b) with ammonia and then contacting the neutralized catalyst-containing aqueous solution with benzophenone-imine to extract the catalyst into benzophenone-imine; and(e) separating the benzophenone-imine solution containing the catalyst obtained after extraction in step (d) from the aqueous layer and recycling said solution to step (a) to reuse as a catalyst for step (a), without isolating the catalyst from said benzophenone-imine solution.
公开/授权文献
- US5724921A Pet leash 公开/授权日:1998-03-10