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    Process for preparing benzophenone-azines
    1.
    发明授权
    Process for preparing benzophenone-azines 失效
    制备二苯甲酮吖嗪的方法

    公开(公告)号：US4727190A

    公开(公告)日：1988-02-23

    申请号：US918656

    申请日：1986-10-14

    申请人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Yoshiyuki Aoki ,  Masafumi Shimpo

    发明人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Yoshiyuki Aoki ,  Masafumi Shimpo

    IPC分类号： C09B17/00 ,  B01J27/122 ,  C01B21/16 ,  C07B61/00 ,  C07C249/16 ,  C07C251/88 ,  C07C109/16

    CPC分类号： C07C251/88 ,  C01B21/16

    摘要： A process for continuously preparing benzophenone-azines comprising oxidizing benzophenone-imines with molecular oxygen or a molecular oxygen-containing gas in the presence of a copper halide catalyst is disclosed. The oxidation reaction is carried out in a multistage system under an oxygen partial pressure gradually decreasing from the former stage to the latter stage and at a conversion gradually decreasing from the former stage to the latter stage, while controlling the conversion so that the molar ratio of the benzophenone-imines to the copper halide in the final stage be maintained at 1 or more. By the process, the continuous reaction can stably be performed at a high conversion of the benzophenone-imines without involving insolubilization and sedimentation of the catalyst.

    摘要翻译： 公开了一种连续制备二苯甲酮吖嗪的方法，包括在卤化铜催化剂存在下用分子氧或含分子氧气体氧化二苯甲酮 - 亚胺。 氧化反应在多级体系​​中，在从前一阶段到后一阶段逐渐降低的氧分压下进行，并且转化率从前一阶段逐渐降低到后一阶段，同时控制转化率，使得 在最后阶段将二苯甲酮 - 亚胺与卤化铜保持在1以上。 通过该方法，连续反应可以稳定地在二苯甲酮 - 亚胺的高转化率下进行，而不会引起催化剂的不溶解和沉淀。

    Process for producing benzophenone-azine
    2.
    发明授权
    Process for producing benzophenone-azine 失效
    二苯甲酮吖嗪的制备方法

    公开(公告)号：US4751326A

    公开(公告)日：1988-06-14

    申请号：US684419

    申请日：1984-12-20

    申请人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Masafumi Shimpo

    发明人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Toshiaki Kohzaki ,  Osamu Aoki ,  Norio Takeda ,  Masafumi Shimpo

    IPC分类号： C07B61/00 ,  B01J27/00 ,  B01J27/32 ,  C07C67/00 ,  C07C241/00 ,  C07C251/88 ,  C07C109/04

    CPC分类号： C07C251/88 ,  B01J27/32 ,  Y02P20/584

    摘要： An improved process for producing benzophenone-azine in which a catalyst can be removed, recovered and recycled is disclosed. The process comprises the steps of:(a) oxidizing benzophenone-imine with molecular oxygen in the presence of cuprous chloride catalyst to produce an oxidation reaction mixture containing benzophenone-azine;(b) contacting the oxidation reaction mixture obtained in step (a) with an aqueous solution containing ammonium chloride and hydrochloric acid to decompose the remaining benzophenone-imine substantially without causing decomposition of the produced benzophenone-azine and simultaneously to extract the catalyst from the oxidation reaction mixture;(c) separating the oxidation reaction mixture containing benzophenone-azine after the extraction in step (b) to recover benzophenone-azine as a solution;(d) neutralizing the catalyst-containing aqueous solution separated after the extraction step (b) with ammonia and then contacting the neutralized catalyst-containing aqueous solution with benzophenone-imine to extract the catalyst into benzophenone-imine; and(e) separating the benzophenone-imine solution containing the catalyst obtained after extraction in step (d) from the aqueous layer and recycling said solution to step (a) to reuse as a catalyst for step (a), without isolating the catalyst from said benzophenone-imine solution.

    摘要翻译： 公开了可以除去，回收和回收催化剂的二苯甲酮 - 吖嗪的改进方法。 该方法包括以下步骤：（a）在氯化亚铜催化剂存在下用分子氧氧化二苯甲酮 - 亚胺以产生含有二苯甲酮 - 吖嗪的氧化反应混合物; （b）将步骤（a）中获得的氧化反应混合物与含有氯化铵和盐酸的水溶液接触，基本上分解剩余的二苯甲酮 - 亚胺，而不会引起生成的二苯甲酮 - 吖嗪的分解，同时从催化剂中提取催化剂 反应混合物; （c）在步骤（b）中提取后分离含有二苯甲酮 - 吖嗪的氧化反应混合物，以二苯甲酮 - 吖嗪为溶液回收; （d）用氨中和提取步骤（b）后分离的含催化剂的水溶液，然后使中和的含有催化剂的水溶液与二苯甲酮 - 亚胺接触，将催化剂萃取到二苯甲酮 - 亚胺中; 和（e）将步骤（d）中提取后得到的含有催化剂的二苯甲酮 - 亚胺溶液从水层中分离出来，并将所述溶液再循环到步骤（a）中以再利用作为步骤（a）的催化剂，而不将催化剂从 称二苯甲酮 - 亚胺溶液。

    Process for preparing hydrazine hydrohalogenide
    4.
    发明授权
    Process for preparing hydrazine hydrohalogenide 失效
    制备氢卤化肼的方法

    公开(公告)号：US4628119A

    公开(公告)日：1986-12-09

    申请号：US702553

    申请日：1985-02-19

    申请人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Osamu Aoki

    发明人： Takanari Nawata ,  Shuzabu Sakaguchi ,  Osamu Aoki

    IPC分类号： B01J23/00 ,  B01J27/122 ,  C01B21/16 ,  C07C109/04

    CPC分类号： C07C251/88 ,  C01B21/16 ,  Y02P20/584

    摘要： A process for preparing hydrazine hydrohalogenide is disclosed. The process comprises the steps of:(a) oxidizing benzophenone-imines with molecular oxygen in the presence of a copper halide catalyst to produce benzophenone-azines;(b) contacting the oxidation reaction mixture with an aqueous solution containing a hydrohalogenic acid thereby hydrolyzing the benzophenone-azines to produce a hydrazine hydrohalogenide and, simultaneously, extracting and removing the catalyst with the hydrohalogenic acid-containing aqueous solution to obtain an aqueous solution containing the hydrazine hydrohalogenide and the catalyst;(c) separating the aqueous solution and adjusting the solution to a pH of from 3 to 7 with an alkali;(d) contacting the aqueous solution with benzophenone-imines to extract the catalyst;(e) separating the catalyst-containing benzophenone-imines solution from the aqueous solution containing the hydrazine hydrohalogenide to recover the hydrazine hydrohalogenide and to recycle the catalyst-containing benzophenone-imines solution to step (a).The process is advantageous in that the catalyst is easily recovered for reuse.

    摘要翻译： 公开了一种制备氢卤酸肼的方法。 该方法包括以下步骤：（a）在卤化铜催化剂存在下用分子氧氧化二苯甲酮 - 亚胺，生成二苯甲酮 - 吖嗪; （b）使氧化反应混合物与含有氢卤酸的水溶液接触，从而水解二苯甲酮 - 吖嗪以产生氢卤酸肼，同时用含氢卤酸的水溶液萃取和除去催化剂，得到含有 肼氢卤化物和催化剂; （c）用碱分离水溶液并将溶液调节至3至7的pH; （d）使该水溶液与二苯甲酮 - 亚胺接触以提取催化剂; （e）从含有氢卤化肼的水溶液中分离含催化剂的二苯甲酮 - 亚胺溶液以回收氢卤酸肼，并将含有催化剂的二苯甲酮 - 亚胺溶液再循环到步骤（a）。 该方法的优点在于催化剂容易回收再利用。

    Fuel cell
    6.
    发明申请
    Fuel cell 审中-公开
    燃料电池

    公开(公告)号：US20060040143A1

    公开(公告)日：2006-02-23

    申请号：US10520618

    申请日：2003-06-09

    申请人： Osamu Aoki ,  Kazuhiko Shinohara

    发明人： Osamu Aoki ,  Kazuhiko Shinohara

    IPC分类号： H01M8/00

    CPC分类号： H01M8/023 ,  H01M8/1007

    摘要： A gas diffusion layer (6) is sandwiched between catalyst electrode layers (5) and separators (1, 2), and side faces (6A, 6B) of the gas diffusion layer (6) are arranged so as to face a gas inlet manifold (7) and outlet manifold (8), and partition the inlet manifold (7) and outlet manifold (8). In the gas diffusion layer (6), gas flows from the side face (6A) facing the inlet manifold (7), flows through the interior, and flows out from the side face (6B) facing the outlet manifold (8).

    摘要翻译： 气体扩散层（6）夹在催化剂电极层（5）和隔板（1,2）之间，气体扩散层（6）的侧面（6A，6B）布置成面对气体 入口歧管（7）和出口歧管（8），并分隔入口歧管（7）和出口歧管（8）。 在气体扩散层（6）中，从面向入口歧管（7）的侧面（6A）流出的气体流过内部，从面向出口歧管（8）的侧面（6B）流出， 。

    Cassette mounting and ejection mechanism
    8.
    发明授权
    Cassette mounting and ejection mechanism 失效
    盒式安装和排出机构

    公开(公告)号：US06429998B1

    公开(公告)日：2002-08-06

    申请号：US09416804

    申请日：1999-10-13

    申请人： Osamu Aoki ,  Fumio Sekiguchi

    发明人： Osamu Aoki ,  Fumio Sekiguchi

    IPC分类号： G11B1700

    CPC分类号： G11B15/67565

    摘要： In a pop-up type cassette mounting and ejection mechanism having a lid member which closes a cassette inserting/taking-out opening of a housing when a cassette holder is located at a cassette mount position, and also is movable away from the housing interlockingly with the movement of the cassette holder to a cassette eject position to open the cassette inserting/taking-out opening, the lid member is mounted on the cassette holder so as to be slidable in a direction parallel to the insertion direction of the cassette into the cassette holder, and one of the two side edges of a reinforcing member of a plate member is rotatably mounted on the lid member while the other side edge is rotatably mounted on the housing, thereby linking the housing and the lid member through the reinforcing member. Further, at the cassette inserting/taking-out opening side of the cassette holder, the recess is formed in the housing and the projection for closing the recess is formed in the lid member. Therefore, the insertion of the fingers into the cassette holder from the cassette inserting/taking-out opening can be further facilitated in combination with the displacement of the lid member from the cassette inserting/taking-out opening in the cassette insertion direction when the cassette holder is pushed out to the cassette eject position out of the housing. Accordingly, the inserting/taking-out operation of the cassette into/from the cassette holder can be further facilitated.

    摘要翻译： 在弹出式盒式安装和弹出机构中，当盒式磁带座位于磁带盒安装位置时，该盒式磁带安装和排出机构具有关闭壳体的磁带插入/取出开口的盖构件，并且还可与 磁带盒保持器移动到盒弹出位置以打开盒插入/取出开口，盖构件安装在磁带盒保持器上，以便能够沿与盒的插入方向平行的方向滑动到磁带盒中 并且板构件的加强构件的两个侧边缘中的一个边缘可旋转地安装在盖构件上，而另一侧边缘可旋转地安装在壳体上，从而通过加强构件连接壳体和盖构件。 此外，在盒座的盒插入/取出开口侧，在壳体中形成凹部，并且在盖构件中形成用于封闭凹部的突起。 因此，与盒式磁带插入方向上的盒式磁带插入/取出开口的位移相结合，可以进一步促进从磁带盒插入/取出开口将指状物插入盒式磁带架中 支架从外壳中推出到出纸位置。 因此，能够进一步促进盒式磁带的插入/取出操作。