发明授权
US4879410A Preparation of primary aralkyl urethanes and ureas and isocyanates derived therefrom 失效
制备主要的芳烷基氨基甲酸酯和脲以及衍生自其的异氰酸酯

Preparation of primary aralkyl urethanes and ureas and isocyanates
derived therefrom
摘要:
A process is disclosed for the preparation of aralkyl mono- and diurethanes or ureas by carbamylmethylation, or acid-catalyzed addition at a temperature of 40.degree. C. to about 100.degree. C. of formaldehyde and esters of carbamic acid to aromatic hydrocarbons. Aralkyl carbamates and ureas formed by this process can be cracked directly to produce aralkyl diisocyanates, or hydrogenated and then cracked to produce aliphatic diisocyanates, or reacted directly with polyols to produce polyurethanes by functioning as blocked isocyanates.
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