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发明授权
US5128491A Process for the preparation of glycidyl ethers of di-secondary alcohols with high monomer content 失效
具有高单体含量的二元醇缩水甘油醚的制备方法

Process for the preparation of glycidyl ethers of di-secondary alcohols with high monomer content
摘要：
The present invention relates to a process for the preparation of a glycidyl ether of a di-secondary alcohol with a monomer content of about 80% to about 90% of the formula (I) ##STR1## comprising the steps of: (a) reacting a di-secondary alcohol of the formula (II) ##STR2## with epichlorohydrin in the presence of an alkali and a phase transfer catalyst to produce a glycidyl ether with a monomer content of about 60% to about 75%; and(b) reacting said glycidyl ether with a monomer content of about 60% to about 75% with epichlorohydrin in the presence of an alkali and benzyltrimethylammonium chloride to produce a glycidyl ether of a di-secondary alcohol with a monomer content of about 80% to about 90%.
摘要（中）：

本发明涉及制备单体含量为式（I）的约80％至约90％的二仲醇的缩水甘油醚的方法，其包括以下步骤：（ a）在碱和相转移催化剂的存在下使式（II）的二仲醇与表氯醇反应，生成单体含量为约60％至约75％的缩水甘油醚， ; 和（b）在碱和苄基三甲基氯化铵存在下，使环氧氯丙烷与表氯醇反应所述缩水甘油醚与约60％至约75％的单体含量，以制备单体含量为约80％的二仲醇缩水甘油醚， 至约90％。

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