发明授权
- 专利标题: Zeolite synthesis using an alcohol or like molecules
- 专利标题(中): 使用醇或类似分子的沸石合成
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申请号: US785361申请日: 1991-10-30
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公开(公告)号: US5160500A公开(公告)日: 1992-11-03
- 发明人: Pochen Chu , Donald J. Klocke , David O. Marler , John P. McWilliams , James C. Vartuli
- 申请人: Pochen Chu , Donald J. Klocke , David O. Marler , John P. McWilliams , James C. Vartuli
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: B01J29/40
- IPC分类号: B01J29/40 ; B01J29/65 ; B01J29/70 ; C01B39/48 ; C07C2/66 ; C07C4/18
摘要:
There is provided a method for preparing a zeolite other than ZSM-5 from a reaction mixture comprising a mixed organic directing agent which is a combination of (a) an organic nitrogen containing compound such as an amine or a quaternary ammonium compound and (b) an alcohol and/or diol. Particular zeolites synthesized by this method include ZSM-22 and ZSM-23. The use of an alcohol or a diol may inhibit the coformation of ZSM-5. Especially when used to prepare ZSM-23, this method enables the preparation of more catalytically active ZSM-23 of reduced crystallite size and also enables the use of lower crystallization temperatures. Particular mixed organic directing agents for the preparation of ZSM-23 are combinations of (a) pyrrolidine and (b) ethanol or ethylene glycol. Other factors which enhance the activity of ZSM-23 include the use of the following in the reaction mixtures for preparing ZSM-23: potassium ions; precipitated silica particles as sources of silica; and spray dried precipitated silica/alumina particles as sources of silica and alumina. The catalytic stability of alumina bound ZSM-23 catalysts is especially enhanced by steaming. Particular reactions which can be catalyzed by ZSM-23 made according to methods described herein include the dealkylation of ethylbenzene and the alkylation of benzene with ethylene.
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