Invention Grant
- Patent Title: Layered cracking catalyst and method of manufacture and use thereof
- Patent Title (中): 层状裂化催化剂及其制造方法和用途
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Application No.: US735225Application Date: 1991-07-24
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Publication No.: US5179054APublication Date: 1993-01-12
- Inventor: Paul H. Schipper , Hartley Owen , Joseph A. Herbst , Garry W. Kirker , Albin Huss, Jr. , Pochen Chu
- Applicant: Paul H. Schipper , Hartley Owen , Joseph A. Herbst , Garry W. Kirker , Albin Huss, Jr. , Pochen Chu
- Applicant Address: VA Fairfax
- Assignee: Mobil Oil Corporation
- Current Assignee: Mobil Oil Corporation
- Current Assignee Address: VA Fairfax
- Main IPC: B01J33/00
- IPC: B01J33/00 ; C10G11/05
Abstract:
A layered catalyst suited to the catalytic cracking of heavy feeds comprises a core and a shell. The shell comprises at least 5 wt % of at least 1 molecular sieve having openings of at least 8 angstroms. The core comprises at least 10 wt % of at least 1 molecular sieve having openings comprising a 12 or less-membered ring and has a reduced, if any, content of said molecular sieve having openings of at least 8 angstroms, relative to its concentration in the shell. Suitable molecular sieve materials having openings of at least 8 angstroms include MCM-41, VPI-5, MCM-9 and layered metal oxides, e.g., pillared clays. The required molecular sieve of the core can include zeolite Y, Ultrastable Y or intermediate pore size zeolites such as ZSM-5. The shell which may further contain a metals passivator can act as a metals sink, and can remove metals from the unit by attrition. The catalyst is preferably prepared by forming the core and then coating or encapsulating the core with a shell material. The shell may also comprise an attritable coating of an amorphous rare earth oxide, aluminum oxide and aluminum phosphate composite, which traps metals.
Public/Granted literature
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