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    Catalytic conversion with improved catalyst
    1.
    发明授权
    Catalytic conversion with improved catalyst 失效
    催化转化催化剂改进

    公开(公告)号：US5348643A

    公开(公告)日：1994-09-20

    申请号：US090872

    申请日：1993-07-13

    申请人： Robert P. L. Absil ,  Joseph A. Herbst

    发明人： Robert P. L. Absil ,  Joseph A. Herbst

    IPC分类号： B01J27/16 ,  B01J29/40 ,  B01J37/00 ,  C10G11/05 ,  C01G11/05

    CPC分类号： B01J27/16 ,  B01J29/40 ,  B01J37/0045 ,  C10G11/05 ,  B01J2229/42

    摘要： A process is provided for converting feedstock hydrocarbon compounds over a catalyst composition which comprises clay and a zeolite component, at least one of which has been treated with a phosphorus-containing compound, for example, ammonium dihydrogen phosphate or phosphoric acid, and which is spray dried at a low pH, preferably lower than about 3. An embodiment of the present invention comprises an improved catalytic cracking process to produce high octane gasoline and increased lower olefins, especially propylene and butylene.

    摘要翻译： 提供了一种用于在包含粘土和沸石组分的催化剂组合物中转化原料烃化合物的方法，其中至少一种已经用含磷化合物，例如磷酸二氢铵或磷酸二氢铵处理，并且是喷雾 在低pH，优选低于约3℃下干燥。本发明的一个实施方案包括改进的催化裂化方法以产生高辛烷值汽油和增加的低级烯烃，特别是丙烯和丁烯。

    Catalytic cracking process utilizing a zeolite beta catalyst synthesized with a chelating agent
    2.
    发明授权
    Catalytic cracking process utilizing a zeolite beta catalyst synthesized with a chelating agent 失效
    使用与螯合剂合成的沸石β催化剂的催化裂化方法

    公开(公告)号：US5232579A

    公开(公告)日：1993-08-03

    申请号：US715189

    申请日：1991-06-14

    申请人： Robert P. L. Absil ,  Joseph A. Herbst ,  Jocelyn A. Kowalski ,  Mae K. Rubin

    发明人： Robert P. L. Absil ,  Joseph A. Herbst ,  Jocelyn A. Kowalski ,  Mae K. Rubin

    IPC分类号： B01J29/70 ,  B01J29/80 ,  C01B39/48

    CPC分类号： B01J29/7007 ,  B01J29/80 ,  C01B39/48 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38

    摘要： A catalytic cracking process for converting a hydrocarbon fraction, preferably boiling in the range of a heavy gas oil, is disclosed in which the cracking catalyst is a large crystal fully crystalline zeolite Beta having a broad range of silica-to-alumina mole ratios, i.e. 20->1000. The zeolite Beta catalyst is synthesized with a nitrogenous organic chelating agent, such as a tertiary alkanolamine, preferably triethanolamine, in the synthesis mixture along with at least one source of organic directing agent such as tetraethylammonium hydroxide, tetraethylammonium bromide and tetraethylammonium fluoride. The zeolite Beta can be used as a stand alone catalyst or an additive catalyst for hydrocarbon cracking reactions along with another molecular seive type catalyst such as a faujasite catalyst or ZSM-5. The large crystal zeolite Beta can also be treated with a source of phosphorus to enhance the properties of the zeolite.

    摘要翻译： 公开了一种用于转化优选在重质瓦斯油范围内沸腾的烃馏分的催化裂化方法，其中裂化催化剂是具有宽范围二氧化硅与氧化铝摩尔比的大晶体完全结晶沸石β，即 20-> 1000。 沸石β催化剂与合成混合物中的含氮有机螯合剂如叔链烷醇胺，优选三乙醇胺一起，与至少一种有机导向剂如四乙基氢氧化铵，四乙基溴化铵和四乙基氟化铵源一起合成。 β沸石可以用作独立催化剂或用于烃裂化反应的添加剂催化剂以及另一种分子筛型催化剂如八面沸石催化剂或ZSM-5。 也可以用磷源处理大的晶体沸石β以增强沸石的性能。

    Multi component catalyst and a process for catalytic cracking of heavy hydrocarbon feed to lighter products
    5.
    发明授权
    Multi component catalyst and a process for catalytic cracking of heavy hydrocarbon feed to lighter products 失效
    多组分催化剂和重质烃进料催化裂化成轻质产物的方法

    公开(公告)号：US5006497A

    公开(公告)日：1991-04-09

    申请号：US292287

    申请日：1988-12-30

    申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    IPC分类号： B01J29/08 ,  B01J29/40 ,  B01J29/46 ,  B01J29/80 ,  C10G11/05

    CPC分类号： B01J29/80 ,  B01J29/46 ,  C10G11/05 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/084 ,  B01J29/40

    摘要： A catalytic cracking catalyst and process are disclosed using a catalyst containing: a matrix, a large pore molecular sieve, a shape selective paraffin cracking/isomerization zeolite and a shape selective aliphatic aromatization zeolite. An exemplary catalyst comprises dealuminized zeolite Y, optionally containing rare earth elements, HZSM-5, and gallium ZSM-5 in a matrix. The matrix contains and protects the relatively fragile zeolite components and acts as a sodium and metals sink. The large pore molecular sieve cracks large hydrocarbons to lighter paraffins and olefins. The shape selective paraffin cracking/isomerization component cracks/isomerizes the paraffins produced by the large pore molecular seive. The shape selective aliphatic aromatization catalyst converts light paraffins and olefins into aromatics. A single shape selective zeolite, e.g., ZSM-5 with a controlled amount of an aromatization component such as gallium, may promote both paraffin cracking/isomerization and aromatization.

    摘要翻译： 公开了使用含有基体，大孔分子筛，形状选择性石蜡裂解/异构化沸石和形状选择性脂族芳构化沸石的催化剂的催化裂化催化剂和方法。 示例性催化剂包括在基质中任选地含有稀土元素，HZSM-5和镓ZSM-5的脱铝沸石Y。 该基质含有并保护相对脆弱的沸石组分并充当钠和金属沉。 大孔分子筛将大型烃裂解成较轻的链烷烃和烯烃。 形状选择性石蜡裂解/异构化组分裂解/异构化由大孔分子生成的链烷烃。 形状选择性脂肪族芳构化催化剂将轻链烷烃和烯烃转化为芳族化合物。 具有受控量的芳构化成分如镓的单形选择性沸石，例如ZSM-5可以促进链烷烃裂解/异构化和芳构化。

    Process to reduce NO.sub.x emissions from a fluid catalytic cracking unit
    8.
    发明授权
    Process to reduce NO.sub.x emissions from a fluid catalytic cracking unit 失效
    从流化催化裂化装置减少NOx排放的方法

    公开(公告)号：US4868144A

    公开(公告)日：1989-09-19

    申请号：US188810

    申请日：1988-06-30

    申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    IPC分类号： C10G11/18

    CPC分类号： C10G11/182

    摘要： A multistage process for reducing NO.sub.x in flue gas from fluid catalytic cracking catalyst regeneration. Flue gas is preferably removed after each stage. NO.sub.x formed in each regeneration stage is converted to N.sub.2 prior to discharge from a stage by operating at least the downstream ends of each regeneration stage at oxygen-lean conditions. Staged regeneration can be achieved by passing spent catalyst through a transport reactor in plug type flow and sequentially contacting the catalyst with a plurality of oxygen-containing streams.

    摘要翻译： 一种用于从流化催化裂化催化剂再生中还原烟道气中的NOx的多级方法。 烟道气优选在每个阶段之后被去除。 在每个再生阶段形成的NOx在通过在贫氧条件下至少操作每个再生阶段的下游端从阶段排出之前转化为N2。 分级再生可以通过将废催化剂通过塞式流动的运输反应器并且使催化剂与多个含氧流顺序接触来实现。

    Maximizing distillate production in a fluid catalytic cracking operation employing a mixed catalyst system
    9.
    发明授权
    Maximizing distillate production in a fluid catalytic cracking operation employing a mixed catalyst system 失效
    在采用混合催化剂体系的流化催化裂化操作中最大化馏出液生产

    公开(公告)号：US4865718A

    公开(公告)日：1989-09-12

    申请号：US153521

    申请日：1988-02-08

    申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    IPC分类号： C10G11/05

    CPC分类号： C10G11/05

    摘要： A fluid catalytic cracking method which comprises:(a) cracking a hydrocarbon feed stock in the presence of a mixed catalyst system which comprises particles of a first, amorphous cracking catalyst and/or large crystalline cracking catalyst component which requires frequent regeneration in a catalyst regeneration zone and particles of a second, shape selective crystalline silicate zeolite catalyst component which is less coke deactivated than the first catalyst component and requires less frequent regeneration than the latter, there being a sufficient difference between one or more of the characterizing physical properties of each catalyst component that the rate of circulation of particles of second catalyst component through the regeneration zone is, on the average, less than that of particles of first catalyst component, said cracking providing a product rich in C.sub.2-6 olefins; and,b) catalytically converting C.sub.2 -C.sub.6 olefins obtained from step (a) to a product containing gasoline and distillate.

    摘要翻译： 一种流化催化裂化方法，其包括：（a）在混合催化剂体系存在下裂化烃原料，该混合催化剂体系包含第一种无定形裂化催化剂和/或需要在催化剂再生中频繁再生的大型结晶裂解催化剂组分的颗粒 区域和第二形状选择性结晶硅酸盐沸石催化剂组分的颗粒，其比第一催化剂组分的焦化活性低，并且需要比后者更少频繁的再生，每种催化剂的一种或多种表征物理性质之间存在充分的差异 组分是第二催化剂组分通过再生区的颗粒的循环速率平均小于第一催化剂组分的颗粒的循环速率，所述裂化提供了富含C2-6烯烃的产物; 和b）将从步骤（a）获得的C2-C6烯烃催化转化成含有汽油和馏出物的产物。

    Multiple riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments
    10.
    发明授权
    Multiple riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments 失效
    使用氢和碳氢贡献碎片的多提液流化催化裂化方法

    公开(公告)号：US4853105A

    公开(公告)日：1989-08-01

    申请号：US148204

    申请日：1988-02-01

    申请人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    发明人： Joseph A. Herbst ,  Hartley Owen ,  Paul H. Schipper

    IPC分类号： C10G11/18 ,  C10G51/06

    CPC分类号： C10G51/06 ,  C10G11/18

    摘要： A catalytic cracking process is provided which comprises:(a) cracking a first heavy hydrocarbon feed in a first riser in the presence of a mixed catalyst composition comprising, as a first catalyst component, an amorphous cracking catalyst and/or a large pore crystalline cracking catalyst and, as a second catalyst component, a shape selective medium pore crystalline silicate zeolite, to provide gasoline boiling range material and one or more light hydrocarbons; and,(b) cracking a thermally treated second heavy hydrocarbon feed in a second riser in the presence of said mixed catalyst composition and in admixture with a gasiform material contributing mobile hydrogen species and/or carbon-hydrogen fragments at the reaction conditions employed to provide gasoline boiling range material in increased yield and/or of higher quality.

    摘要翻译： 提供了一种催化裂化方法，其包括：（a）在混合催化剂组合物存在下，在第一提升管中裂解第一重烃进料，所述混合催化剂组合物包含作为第一催化剂组分的无定形裂化催化剂和/或大孔结晶裂解 催化剂和作为第二催化剂组分的形状选择性中孔结晶硅酸盐沸石，以提供汽油沸程物料和一种或多种轻烃; 和（b）在所述混合催化剂组合物的存在下，在第二提升管中裂化经热处理的第二重烃进料，并且与用于提供活性氢物质和/或碳氢氢碎片的气态物质混合， 汽油沸腾物料的产量提高和/或质量较高。