发明授权
- 专利标题: Case-hardened gelatin-grafted polymer particles
- 专利标题(中): 表面硬化的明胶接枝聚合物颗粒
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申请号: US718489申请日: 1991-06-20
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公开(公告)号: US5248558A公开(公告)日: 1993-09-28
- 发明人: Pranab Bagchi , William L. Gardner
- 申请人: Pranab Bagchi , William L. Gardner
- 申请人地址: NY Rochester
- 专利权人: Eastman Kodak Company
- 当前专利权人: Eastman Kodak Company
- 当前专利权人地址: NY Rochester
- 主分类号: G03C1/047
- IPC分类号: G03C1/047 ; G03C1/053 ; G03C1/95
摘要:
It has been shown by Photon Correlation Spectroscopy than when additional hardener is added to below saturation gel-grafted polymer particles, the gel layer shrinks due to hardening, as there is no free gel left in solution. In films, such case-hardened gelatin-grafted soft polymer particles can act as highly elastic stress absorbing fillers. This is because the dry case-hardened shell is expected to form a thin hard shell around the soft polymer particles. It is shown that gelatin-grafted soft polymer particles and case-hardened gelatin-grafted soft polymer particles, incorporated in the emulsion layers of pressure sensitive photographic products, produce coatings with highly reduced pressure sensitivity without any developability or delamination concerns. In this invention the case-hardened gelatin-grafted polymer particles are preferred over the simple gelatin-grafted material. The core polymer particle can have diameters anywhere between 10 to 10.sup.8 nm with a monolayer of gelatin shell that is chemically bonded to its surface and the gelatin shell is further cross-linked with each other to hydrated thicknesses of between 5 to 20 nm.
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