发明授权
- 专利标题: Gasoline upgrading process
- 专利标题(中): 汽油升级过程
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申请号: US963229申请日: 1992-10-19
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公开(公告)号: US5320742A公开(公告)日: 1994-06-14
- 发明人: David L. Fletcher , Timothy L. Hilbert , David A. Pappal , David W. Rumsey , Gerald J. Teitman
- 申请人: David L. Fletcher , Timothy L. Hilbert , David A. Pappal , David W. Rumsey , Gerald J. Teitman
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: C10G35/04
- IPC分类号: C10G35/04 ; C10G59/00 ; C10G65/04 ; C10G67/12 ; C10G69/08 ; C10G35/00 ; C10G45/00
摘要:
A sulfur-containing catalytically cracked naphtha is upgraded to form a low-sulfur gasoline product by a process which retains the octane contribution from the olefinic front end of the naphtha. Initially, the mercaptan sulfur in the front end of the cracked naphtha is converted to higher boiling disulfides by oxidation. The front end, which is then essentially an olefinic, high octane sulfur-free material, may be blended directly into the gasoline pool. The back end, which now contains the original higher boiling sulfur components such as thiophenes, together with the sulfur transferred from the front end as disulfides, is hydrotreated to produce a desulfurized product. This desulfurized product, which has undergone a loss in octane by saturation of olefins, is then treated in a second stage, by contact with a catalyst of acidic functionality, preferably a zeolite such as ZSM-5, under conditions which produce a product in the gasoline boiling range of higher octane value. Because this second product may contain combined organic sulfur, it may be subjected to a final desulfurization to reduce organic sulfur to acceptable levels.
公开/授权文献
- US5926869A Table 公开/授权日:1999-07-27
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