发明授权
- 专利标题: Crystalline zeolite-like gallosilicate, and method for its synthesis
- 专利标题(中): 结晶沸石状硅酸盐及其合成方法
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申请号: US903792申请日: 1992-06-24
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公开(公告)号: US5365002A公开(公告)日: 1994-11-15
- 发明人: Martin Wallau , Rudolf Spichtinger , Klaus K. Unger , Arno Tissler , Roland Thome
- 申请人: Martin Wallau , Rudolf Spichtinger , Klaus K. Unger , Arno Tissler , Roland Thome
- 申请人地址: DEX Bonn DEX Gelsenkirchen-Hassel
- 专利权人: VAW Aluminium AG,Veba OEL AG
- 当前专利权人: VAW Aluminium AG,Veba OEL AG
- 当前专利权人地址: DEX Bonn DEX Gelsenkirchen-Hassel
- 优先权: DEX4120847 19910625
- 主分类号: B01J20/10
- IPC分类号: B01J20/10 ; B01J29/87 ; C01B33/20 ; C01B39/00 ; C01B39/06 ; C01B39/08 ; C07C2/00 ; C10G35/06 ; C07C2/76 ; B01J29/04
摘要:
The invention relates to a crystalline zeolite-like gallosilicate having an atomic ratio of Si/Ga in the outer crystalline surface that is not larger than the average Si/Ga ratio for the whole of the crystal. The invention also relates to a method of making such a gallosilicate comprising the hydrothermal crystallization of a strictly inorganic reaction mixture having the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05-1.0; and H.sub.2 O/SiO.sub.2 =10-1,000. The invention further relates to the above-described method wherein said reaction mixture is prepared by adding an aged gel to a first mixture, the first mixture preferably having a composition with the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05 to 1.0; and H.sub.2 O/SiO.sub.2 =20 to 100.
公开/授权文献
- US5851112A Dental handpiece 公开/授权日:1998-12-22