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公开(公告)号：US5466432A
公开(公告)日：1995-11-14
申请号：US287232
申请日：1994-08-08
IPC分类号： B01J20/10 , B01J29/87 , C01B33/20 , C01B39/00 , C01B39/06 , C01B39/08 , C07C2/00 , C10G35/06 , C01B39/36
CPC分类号： C10G35/065 , B01J29/87 , C01B39/082 , C07C2/00 , C07C2529/87 , Y10S423/22
摘要： The invention relates to a crystalline zeolite-like gallosilicate having an atomic ratio of Si/Ga in the outer crystalline surface that is not larger than the average Si/Ga ratio for the whole of the crystal. The invention also relates to a method of making such a gallosilicate comprising the hydrothermal crystallization of a strictly inorganic reaction mixture having the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05-1.0; and H.sub.2 O/SiO.sub.2 =10-1,000. The invention further relates to the above-described method wherein said reaction mixture is prepared by adding an aged gel to a first mixture, the first mixture preferably having a composition with the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05 to 1.0; and H.sub.2 O/SiO.sub.2 =20 to 100.
摘要翻译： 本发明涉及外晶面中Si / Ga原子比不大于整个晶体的平均Si / Ga比的结晶沸石状半硅酸盐。 本发明还涉及一种制备这种硅酸盐硅酸盐的方法，其包括具有以下摩尔比的严格无机反应混合物的水热结晶：SiO 2 / Ga 2 O 3> = 5; OH- / SiO 2 = 0.05-1.0; 和H2O / SiO2 = 10-1,000。 本发明还涉及上述方法，其中所述反应混合物通过将老化凝胶加入到第一混合物中制备，第一混合物优选具有以下摩尔比的组成：SiO 2 / Ga 2 O 3> = 5; OH- / SiO 2 = 0.05〜1.0; 和H 2 O / SiO 2 = 20〜100。
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2.发明授权Method for the preparation of crystalline gallosilicates, and their use for the preparation of catalysts and adsorbents 失效制备结晶硅酸镓盐的方法及其用于制备催化剂和吸附剂的用途
公开(公告)号：US5273737A
公开(公告)日：1993-12-28
申请号：US725036
申请日：1991-07-03
IPC分类号： B01J20/18 , B01J29/04 , B01J29/87 , C01B33/20 , C01B39/02 , C01B39/04 , C01B39/06 , C01B39/08 , C01B39/36 , C07B61/00 , C07C2/00 , C07C2/84 , C07C15/00 , C10G50/00 , C01B33/24 , C01F7/00
CPC分类号： C01B39/082 , B01J29/87 , C07C2/00 , C10G50/00 , C07C2529/87
摘要： Disclosed is a method for preparing crystalline gallosilicates having a molar ratio of SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5 an having a more uniform particle size with enhanced catalytic activity. According to the method of the invention, crystalline gallosilicates are prepared by adding an aged, gallosilicate nuclei-forming gel having a molar ratio of SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5 to an aqueous, alkaline solution containing reactive silicon and gallium compounds to form a mixture. The mixture is then subjected to hydrothermal crystallization conditions to form the crystalline gallosilicate. The gallosilicates prepared by the disclosed method is useful for the preparation of catalysts and adsorbents and in processes for converting low molecular weight hydrocarbons to higher aliphatics and aromatic compounds.
摘要翻译： 公开了一种制备具有更均匀粒径的具有增强的催化活性的SiO 2 / Ga 2 O 3> / = 5的摩尔比的结晶硅酸镓盐酸盐的方法。 根据本发明的方法，通过向含有反应性硅和镓化合物的含水碱性溶液中加入具有SiO 2 / Ga 2 O 3> = 5摩尔比的老化的硅酸盐硅酸盐成核凝胶，形成结晶的硅酸镓，形成混合物 。 然后将混合物进行水热结晶条件以形成结晶硅酸盐。 通过公开的方法制备的硅铝酸盐可用于制备催化剂和吸附剂以及将低分子量烃转化为较高脂肪族和芳族化合物的方法。
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公开(公告)号：US5365002A
公开(公告)日：1994-11-15
申请号：US903792
申请日：1992-06-24
IPC分类号： B01J20/10 , B01J29/87 , C01B33/20 , C01B39/00 , C01B39/06 , C01B39/08 , C07C2/00 , C10G35/06 , C07C2/76 , B01J29/04
CPC分类号： C10G35/065 , B01J29/87 , C01B39/082 , C07C2/00 , C07C2529/87 , Y10S423/22
摘要： The invention relates to a crystalline zeolite-like gallosilicate having an atomic ratio of Si/Ga in the outer crystalline surface that is not larger than the average Si/Ga ratio for the whole of the crystal. The invention also relates to a method of making such a gallosilicate comprising the hydrothermal crystallization of a strictly inorganic reaction mixture having the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05-1.0; and H.sub.2 O/SiO.sub.2 =10-1,000. The invention further relates to the above-described method wherein said reaction mixture is prepared by adding an aged gel to a first mixture, the first mixture preferably having a composition with the following molar ratios: SiO.sub.2 /Ga.sub.2 O.sub.3 .gtoreq.5; OH.sup.- /SiO.sub.2 =0.05 to 1.0; and H.sub.2 O/SiO.sub.2 =20 to 100.
摘要翻译： 本发明涉及外晶面中Si / Ga原子比不大于整个晶体的平均Si / Ga比的结晶沸石状半硅酸盐。 本发明还涉及一种制备这种硅酸盐硅酸盐的方法，其包括具有以下摩尔比的严格无机反应混合物的水热结晶：SiO 2 / Ga 2 O 3> = 5; OH- / SiO 2 = 0.05-1.0; 和H2O / SiO2 = 10-1,000。 本发明还涉及上述方法，其中所述反应混合物通过将老化凝胶加入到第一混合物中制备，第一混合物优选具有以下摩尔比的组成：SiO 2 / Ga 2 O 3> = 5; OH- / SiO 2 = 0.05〜1.0; 和H 2 O / SiO 2 = 20〜100。
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公开(公告)号：US5409687A
公开(公告)日：1995-04-25
申请号：US255306
申请日：1994-06-07
申请人： Martin Wallau , Arno Tissler , Roland Thome , Klaus K. Unger
发明人： Martin Wallau , Arno Tissler , Roland Thome , Klaus K. Unger
CPC分类号： B01J29/87 , C01B39/082 , Y10S423/22
摘要： Gallosilicates can be formed in the absence of structure-guiding organic hydrocarbons or amines by(a) combining water, a base, a gallium material selected from the group consisting of alkali metal gallates, Ga.sub.2 O.sub.3 and hydrated derivatives of Ga.sub.2 O.sub.3, and gallium salts optionally in aqueous solution, with a powder consisting essentially of particles of silicon dioxide or a hydrated derivative thereof having a diameter of 0.1 to 5 microns and a specific surface area of 20-22 m.sup.2 /g in amounts such that the atomic ratio of silicon to gallium is at least 10 to form an alkaline aqueous reaction mixture; and(b) heating the reaction mixture to produce zeolite-like gallosilicates. These materials are advantageously recovered from the reaction mixture and subjected to ion exchange to replace any alkali metal or alkaline-earth metal ions present with protons.
摘要翻译： 可以通过（a）将水，碱，选自碱金属镓酸盐，Ga 2 O 3和Ga 2 O 3的水合衍生物的镓材料和镓盐任意地混合在一起，形成不含结构导向有机烃或胺的高硅酸盐 水溶液，其基本上由二氧化硅或其水合衍生物的颗粒组成，其直径为0.1至5微米，比表面积为20-22m 2 / g，其量使得硅与镓的原子比为 至少10以形成碱性水性反应混合物; 和（b）加热反应混合物以产生沸石状的硅酸盐。 这些材料有利地从反应混合物中回收并进行离子交换以取代质子中存在的任何碱金属或碱土金属离子。
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