发明授权
US5382743A Skeletal isomerization of n-pentenes using ZSM-35 in the presence of
hydrogen
失效
在氢存在下使用ZSM-35对正戊烯的骨架异构化
- 专利标题: Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen
- 专利标题(中): 在氢存在下使用ZSM-35对正戊烯的骨架异构化
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申请号: US51930申请日: 1993-04-26
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公开(公告)号: US5382743A公开(公告)日: 1995-01-17
- 发明人: James H. Beech, Jr. , Roland B. Saeger , Robert A. Ware
- 申请人: James H. Beech, Jr. , Roland B. Saeger , Robert A. Ware
- 申请人地址: VA Fairfax
- 专利权人: Mobil Oil Corporation
- 当前专利权人: Mobil Oil Corporation
- 当前专利权人地址: VA Fairfax
- 主分类号: B01J29/40
- IPC分类号: B01J29/40 ; C07B61/00 ; C07C5/27 ; C07C11/10 ; C07C5/22
摘要:
A method for conversion of linear C5 olefins in the presence of contaminant diolefins to corresponding iso-olefins of the same carbon number which comprises contacting a linear C5 olefin-containing organic feedstock with a catalyst comprising material having the structure of ZSM-35 under skeletal isomerization conditions, wherein said conversion is carried out at temperatures between about 100.degree. and 750.degree. C., weight hourly space velocities (WHSV) based on linear C5 olefins in said feedstock between 0.1 and 500 WHSV, C5 linear olefin partial pressures between 2 and 2000 kPa, and in the presence of hydrogen added in an amount sufficient to enhance linear C5 olefin conversion activity and extend the catalyst life of the catalyst relative to operation without any hydrogen added.
公开/授权文献
- USD380151S Crystal container 公开/授权日:1997-06-24