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1.发明授权Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen 失效在氢存在下使用ZSM-35对正戊烯的骨架异构化
公开(公告)号：US5382743A
公开(公告)日：1995-01-17
申请号：US51930
申请日：1993-04-26
CPC分类号： C07C5/2775
摘要： A method for conversion of linear C5 olefins in the presence of contaminant diolefins to corresponding iso-olefins of the same carbon number which comprises contacting a linear C5 olefin-containing organic feedstock with a catalyst comprising material having the structure of ZSM-35 under skeletal isomerization conditions, wherein said conversion is carried out at temperatures between about 100.degree. and 750.degree. C., weight hourly space velocities (WHSV) based on linear C5 olefins in said feedstock between 0.1 and 500 WHSV, C5 linear olefin partial pressures between 2 and 2000 kPa, and in the presence of hydrogen added in an amount sufficient to enhance linear C5 olefin conversion activity and extend the catalyst life of the catalyst relative to operation without any hydrogen added.
摘要翻译： 在存在污染二烯烃的情况下将线性C 5烯烃转化为相同碳数的相应异烯烃的方法，其包括使含有直链C 5烯烃的有机原料与包含具有ZSM-35结构的材料的催化剂在骨架异构化 条件，其中所述转化在约100℃和750℃之间的温度下进行，基于在所述原料中的线性C 5烯烃在0.1至500WHSV之间的重小时空速（WHSV），2至2000之间的C5线性烯烃分压 kPa，并且在氢气存在下加入的量足以提高线性C5烯烃转化活性，并延长催化剂相对于操作的催化剂寿命而没有加入任何氢气。
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公开(公告)号：US5405814A
公开(公告)日：1995-04-11
申请号：US72379
申请日：1993-06-07
CPC分类号： C07C41/05 , C07C41/09 , Y02P20/584
摘要： An olefin hydration catalyst is regenerated with a non-oxidizing light gas, such as hydrogen. Light olefins, especially propylene, are converted to a mixture of alcohol(s), such as isopropanol (IPA) and ether(s), such as diisopropylether (DIPE) by contacting a feed containing the olefin with water and/or alcohol with the olefin hydration catalyst. Regeneration conditions include temperatures of from about 150.degree. C. to about 550.degree. C., pressures below about 1000 psig (6900 kPa). Lower pressures of regeneration unexpectedly demonstrated more effective catalyst regeneration through greater coke removal.
摘要翻译： 烯烃水合催化剂用非氧化性轻质气体如氢气再生。 通过使含有烯烃的进料与水和/或醇接触，将轻质烯烃，特别是丙烯转化成醇，如异丙醇（IPA）和醚，如二异丙基醚（DIPE））的混合物， 烯烃水合催化剂。 再生条件包括约150℃至约550℃的温度，低于约1000psig（6900kPa）的压力。 更低的再生压力意外地通过更大的焦炭去除表明更有效的催化剂再生。
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公开(公告)号：US5625113A
公开(公告)日：1997-04-29
申请号：US365334
申请日：1994-12-28
CPC分类号： C07C2/58 , C07C2/62 , C07C9/16 , C07C2527/054 , C07C2529/70
摘要： A process is disclosed for alkylating an isoparaffin with an olefin comprising the steps of:(a) reacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in a first alkylation reaction stage at temperature from about -40.degree. C. to about 500.degree. C. and overall isoparaffin:olefin feed weight ratio of from about 1:1 to about 250:1 with a solid alkylation catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 35, X is a trivalent element and Y is a tetravalent element;(b) mixing the effluent from said first alkylation stage with additional olefin to evolve an intermediate stream having an isoparaffin:olefin weight ratio of from about 2:1 to about 100:1; and(c) reacting said intermediate stream in a second alkylation stage in the absence of intermediate fractionation with a liquid acid catalyst comprising H.sub.2 SO.sub.4 to produce C.sub.5 + alkylate.
摘要翻译： 公开了一种用烯烃烷基化异链烷烃的方法，该方法包括以下步骤：（a）使第一烷基化反应阶段中具有4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃反应， 40℃至约500℃，总异构链烷烃：烯烃进料重量比为约1:1至约250:1，其中固体烷基化催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括值 基本上如说明书的表I所述，并且具有包含摩尔关系X 2 O 3：（n）YO 2的组成，其中n小于约35，X是三价元素，Y是四价元素; （b）将来自所述第一烷基化阶段的流出物与另外的烯烃混合以产生具有约2:1至约100:1的异链烷烃：烯烃重量比的中间料流; 和（c）在不与中间分级分离的第二烷基化阶段中使所述中间物流与包含H 2 SO 4的液体酸催化剂反应，以产生C5 +烷基化物。
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公开(公告)号：US5288924A
公开(公告)日：1994-02-22
申请号：US946705
申请日：1992-09-18
CPC分类号： C07C41/05 , C07C29/04 , C07C41/06 , B01J2229/42 , B01J29/7007
摘要： A method for starting up a fixed bed propylene hydration reactor containing shape selective metallosilicate catalyst particles for the production of isopropanol and/or diisopropyl ether is disclosed comprising the following sequential steps: contacting a feedstream comprising propane with catalyst particles in a hydration reactor; then introducing a feedstream comprising isopropanol into the reactor to displace propane. Next, a feedstream comprising propylene is introduced into the reactor under etherification conditions. Finally, a feedstream is introduced in the reactor comprising water under etherification and hydration reaction conditions whereby diisopropyl ether and isopropanol are produced.
摘要翻译： 公开了一种用于启动含有用于生产异丙醇和/或二异丙醚的形状选择性金属硅酸盐催化剂颗粒的固定床丙烯水合反应器的方法，其包括以下顺序步骤：使包含丙烷的进料流与水合反应器中的催化剂颗粒接触; 然后将包含异丙醇的进料流引入反应器以置换丙烷。 接下来，在醚化条件下将包含丙烯的进料流引入反应器中。 最后，在醚化和水合反应条件下将反应器中的水引入反应器中，由此产生二异丙醚和异丙醇。
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5.发明授权
公开(公告)号：US5420360A
公开(公告)日：1995-05-30
申请号：US112286
申请日：1993-08-27
IPC分类号： C07C41/06
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/127
摘要： A process is disclosed for producing alkyl tertiary alkyl ether such as TAME from alkanol and hydrocarbon feedstock containing linear olefins, iso-olefins, linear alkanes and iso-alkanes such as C5 streams from FCC. The process selectively etherifies iso-olefins in a plural stage etherification zone whose linear olefin-containing effluent is treated by distillation to remove iso-alkanes, and alkanol before passing to a skeletal isomerization zone using constrained intermediate pore size zeolite catalyst such as ZSM-22, ZSM-23, or ZSM-35, which converts linear olefins to iso-olefins which are cycled for etherification. The use of distillation to remove iso-alkanes and alkanol reduces mass flow to the etherification process and minimizes skeletal isomerization catalyst poisoning by alkanol, without resort to water extraction processes which require subsequent treatment of the isomerization zone feed to remove water.
摘要翻译： 公开了一种从链烷醇生产烷基叔烷基醚如TAME的方法，以及含有直链烯烃，异烯烃，直链烷烃和异烷烃如FCC的C5流的烃原料。 该方法选择性地醚化多级醚化区中的异烯烃，其直链烯烃流出物通过蒸馏处理以除去异烷烃，和链烷醇在使用约束的中等孔径沸石催化剂如ZSM-22进入骨架异构化区之前 ，ZSM-23或ZSM-35，其将线性烯烃转化为异烯烃，其循环用于醚化。 使用蒸馏来除去异烷烃和链烷醇减少了醚化过程的质量流动，并且使骨架异构化催化剂由链烷醇中毒最小化，而不用采用需要随后处理异构化区域进料以除去水的水提取方法。
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公开(公告)号：US08101048B2
公开(公告)日：2012-01-24
申请号：US12215827
申请日：2008-06-30
申请人： Francis Joseph Lipiecki , Stephen G Maroldo , Deodatta Vinayak Shenai-Khatkhate , Robert A. Ware
发明人： Francis Joseph Lipiecki , Stephen G Maroldo , Deodatta Vinayak Shenai-Khatkhate , Robert A. Ware
IPC分类号： B01D3/00
摘要： This invention relates to methods of removing impurities from compounds having similar volatilities to form ultra high purity compounds.
摘要翻译： 本发明涉及从具有相似挥发性的化合物中除去杂质以形成超高纯度化合物的方法。
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公开(公告)号：US06835863B2
公开(公告)日：2004-12-28
申请号：US09351147
申请日：1999-07-12
申请人： Art W. Chester , Ke Liu , Robert A. Ware
发明人： Art W. Chester , Ke Liu , Robert A. Ware
IPC分类号： C07C406
CPC分类号： C10G35/095
摘要： A C4+ naphtha hydrocarbon feed is converted to light olefins and aromatics, by contacting the feed with a catalyst containing ZSM-5 and/or ZSM-11, a substantially inert matrix material such as silica and/or clay, having less than about 20 wt % active matrix material based on total catalyst composition, and phosphorus.
摘要翻译： 通过使进料与含有ZSM-5和/或ZSM-11的催化剂（基本上惰性的基质材料如二氧化硅和/或粘土）接触，将C4 +石脑油进料转化为轻质烯烃和芳族化合物，其具有小于约20wt 基于总催化剂组成和磷的％活性基质材料。
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公开(公告)号：US5414172A
公开(公告)日：1995-05-09
申请号：US184902
申请日：1994-01-21
CPC分类号： C10G59/02
摘要： A process for upgrading low octane naphthas to produce gasoline products with low levels of benzene and aromatics while retaining a high pool octane uses a paraffinic naphtha reformer feed which is dehexanized to provide a C.sub.7 + fraction which is fed to the reformer and a C.sub.6 fraction which is fed together with the C.sub.6 fraction from the reformer effluent to a catalytic upgrading step where the low octane components from the naphtha and the benzene from the reformate are converted to a low benzene, high octane gasoline by alkylation of the benzene and other aromatics present in the reformate. The process has the advantage that benzene make in the reformer is reduced by the partial by-passing of the C.sub.6 benzene precursors around the reformer; in addition, improved benzene alkylation results from the presence of additional light olefins generated by the cracking of paraffins from the paraffinic naphtha. the reaction is preferably carried out in a turbulent fluidized bed reaction zone.
摘要翻译： 一种用于升级低辛烷值的石脑油以生产具有低含量苯和芳族化合物的汽油产品同时保留高残留辛烷值的方法使用石蜡石脑油重整器原料，该进料被脱脂以提供进料至重整器的C 7+馏分， 与来自重整器流出物的C6馏分一起进料到催化升级步骤，其中来自石脑油的低辛烷值成分和来自重整产物的苯通过苯和其它芳族化合物的烷基化转化为低苯，高辛烷值汽油 重组。 该方法的优点是在重整器周围的C6苯前体的部分旁路减少了重整器中的苯; 此外，改进的苯烷基化是由于由链烷烃石脑油裂解石蜡产生的另外的轻质烯烃的存在。 该反应优选在湍流流化床反应区中进行。
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公开(公告)号：US5011593A
公开(公告)日：1991-04-30
申请号：US442870
申请日：1989-11-20
申请人： Robert A. Ware , Stephen S. Wong
发明人： Robert A. Ware , Stephen S. Wong
CPC分类号： C10G45/12 , B01J29/7815 , B01J2229/26 , B01J2229/42 , F02B3/06
摘要： A hydrodesulfurization process for catalytically hydrosulfurizing highly aromatic feeds, especially catalytically cracked feeds such as light cycle oils from catalytic cracking processes and aromatic extracts, employs a hydrodesulfurization catalyst containing zeolite beta. The zeolite beta based catalyst is more effective for effecting desulfurization than comparable amorphous catalysts or catalysts based on other large pore size zeolite and is capable of achieving a high degree of desulfurization at relatively low levels of conversion. The hydrodesulfurization catalyst comprises a transition metal hydrogenation component, preferably Co/Mo, on zeolite beta together with an inert matrix. The zeolite beta based catalyst may be mixed with amorphous catalyst such as Co/Mo/alumina. The low sulfur products are useful as blending components for road diesel fuels and other distillate fuels.
摘要翻译： 用于催化加氢硫化高芳族化合物进料，特别是催化裂化进料如来自催化裂化方法的轻质循环油和芳族萃取物的加氢脱硫方法使用含有β沸石的加氢脱硫催化剂。 基于沸石β的催化剂与基于其它大孔径沸石的可比无定形催化剂或催化剂相比，更有效地实现脱硫，并且能够在相当低的转化水平下实现高度脱硫。 加氢脱硫催化剂在沸石β上与惰性基质一起包含过渡金属氢化组分，优选Co / Mo。 沸石β型催化剂可与无定形催化剂如Co / Mo /氧化铝混合。 低硫产品可用作道路柴油燃料和其他馏出燃料的混合组分。
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公开(公告)号：US4913794A
公开(公告)日：1990-04-03
申请号：US379511
申请日：1989-07-13
申请人： Quang N. Le , Robert A. Ware , Stephen S. Wong
发明人： Quang N. Le , Robert A. Ware , Stephen S. Wong
CPC分类号： C10G71/00 , C10G2400/10
摘要： A process is disclosed for improving the Viscosity Index of a hydrocarbon lubricating oil comprising the steps of providing a flow reactor having separate first and second inlet ports for the separate co-injection of lubricating oil and an organic peroxide, charging said lubricating oil and said organic peroxide of said flow reactor through said first and second inlet ports respectively, controlling the relative flowrates of said lubricating oil and organic peroxide reactants together with the total volumetric flowrate through said flow reactor to maintain a flow regime which favors diffusional mixing between said organic peroxide and said lubricating oil, and maintaining said organic peroxide and said lubricating oil under conversion conditions including temperatures of between about 50.degree. and 300.degree. C. and pressure sufficient to maintain said lubricating oil and said organic peroxide substantially in the liquid phase. Controlling the flow regime to favor diffusional rather than convective mixing between the lubricating oil and the organic peroxide has surprisingly been found to markedly enhance Viscosity Index improvement.
摘要翻译： 公开了一种用于改进烃类润滑油的粘度指数的方法，该方法包括以下步骤：提供具有单独的第一和第二入口的流动反应器，用于单独共同注入润滑油和有机过氧化物，将所述润滑油和所述有机物 所述流动反应器分别通过所述第一和第二入口过氧化物，控制所述润滑油和有机过氧化物反应物的相对流速以及通过所述流动反应器的总体积流量，以保持有利于所述有机过氧化物和 所述润滑油，并且在包括约50℃至300℃的温度的转化条件下保持所述有机过氧化物和所述润滑油以及足以使所述润滑油和所述有机过氧化物基本上处于液相的压力。 令人惊讶地发现控制流动状态以有利于润滑油和有机过氧化物之间的扩散而不是对流混合，显着提高了粘度指数的改善。
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