发明授权
- 专利标题: Insecticidal N'-substituted-N,N'-diacylhydrazines
- 专利标题(中): 杀虫N'取代-N,N'-二酰基肼
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申请号: US129549申请日: 1993-09-29
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公开(公告)号: US5530028A公开(公告)日: 1996-06-25
- 发明人: Zev Lidert , Dat P. Le , Robert E. Hormann , Thomas R. Opie
- 申请人: Zev Lidert , Dat P. Le , Robert E. Hormann , Thomas R. Opie
- 申请人地址: PA Philadelphia
- 专利权人: Rohm and Haas Company
- 当前专利权人: Rohm and Haas Company
- 当前专利权人地址: PA Philadelphia
- 主分类号: A01N37/28
- IPC分类号: A01N37/28 ; A01N33/00 ; A01N37/40 ; A01N43/30 ; A01N43/32 ; C07C243/38 ; C07C251/86 ; C07C255/24 ; C07C275/28 ; C07C311/51 ; C07C323/48 ; C07C327/56 ; C07D207/34 ; C07D213/54 ; C07D213/87 ; C07D241/24 ; C07D303/38 ; C07D307/58 ; C07D307/68 ; C07D307/79 ; C07D311/58 ; C07D317/50 ; C07D317/68 ; C07D319/18 ; C07D321/10 ; C07D333/38 ; A01N33/26 ; C07C243/16
摘要:
Insecticidal compounds having the formula N-(2-R.sup.a -3-R.sup.b -4-R.sup.h -benzoyl)-N'-(2-R.sup.c -3-R.sup.d -4-R.sup.e -5-R.sup.f -benzoyl)-N'-R.sup.g -hydrazine wherein R.sup.a is a halo or lower alkyl; R.sup. b is lower alkoxy, optionally substituted with halo (preferably fluoro); R.sup.c is selected from hydrogen, halo, lower alkyl, lower alkoxy, lower alkoxy lower alkyl, and nitro; R.sup.d, R.sup.e and R.sup.f are each independently selected from hydrogen, bromo, chloro, fluoro, lower alkyl, lower alkoxy, and lower alkoxy lower alkyl; R.sub.g is a (C.sub.4 -C.sub.6)alkyl; R.sup.h is hydrogen, lower alkoxy, lower alkyl, or when taken together with R.sup.b is methylenedioxy (--OCH.sub.2 O--), 1,2-ethylenedioxy (--OCH.sub.2 CH.sub.2 O--), 1,2-ethyleneoxy (--CH.sub.2 CH.sub.2 O--) or 1,3-propyleneoxy (--CH.sub.2 CH.sub.2 CH.sub.2 O--) wherein an oxo atom is located at the R.sup.b position; and the substituents R.sup.c and R.sup.d, or R.sup.d and R.sup.e, or R.sup.e and R.sup.f when taken together can be methylenedioxy or 1,2-ethylenedioxy as well as compositions comprising an agronomically acceptable carrier and an insecticidally effective amount of such compounds; and methods of using such compounds and compositions.Also, methods for the production of the compounds and their intermediates, which methods comprise either admixing a 3-amino-2-(substituted)-benzoic acid, sodium nitrite and methanol under acidic conditions or admixing a 3,4-fused heterocyclic benzoic acid and an alkyl lithium reagent followed by subsequent reaction with an electrophilic reagent.
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