发明授权
- 专利标题: Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate
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申请号: US703842申请日: 1996-08-27
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公开(公告)号: US5710318A公开(公告)日: 1998-01-20
- 发明人: Larry M. Cirjak , Michael F. Lemanski , David R. Wagner , Nancy C. Benkalowycz , Patricia R. Blum , Marc A. Pepera , Christos Paparizos
- 申请人: Larry M. Cirjak , Michael F. Lemanski , David R. Wagner , Nancy C. Benkalowycz , Patricia R. Blum , Marc A. Pepera , Christos Paparizos
- 申请人地址: OH Cleveland
- 专利权人: The Standard Oil Company
- 当前专利权人: The Standard Oil Company
- 当前专利权人地址: OH Cleveland
- 主分类号: B01J23/58
- IPC分类号: B01J23/58 ; B01J8/24 ; B01J8/32 ; B01J8/38 ; B01J19/00 ; C07B61/00 ; C07C67/05 ; C07C67/055 ; C07C67/313 ; C07C69/15
摘要:
A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding a gaseous mixture comprising ethylene and acetic acid into a fluid bed reactor through a first inlet, introducing the oxygen into the reactor through a second inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material has a range of 60% of the particles being below 200 microns (0.1 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).
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